Abstract A flamelet-based approach that accounts for turbulence-chemistry interaction has been formulated to simulate NOx formation in turbulent lean premixed combustion. In the simulations, the species NO is transported and solved with the chemical source term being modelled through its formation in flame fronts and its formation rate in post-flame regions. The flame-front NO and post-flame NO...

The speed of propagation of a premixed turbulent flame correlates with the intensity of the turbulence encountered by the flame. One consequence of this property is that premixed flames in both laboratory experiments and practical combustors require some type of stabilization mechanism to prevent blow-off and flashback. The stabilization devices often introduce a level of geometric complexity t...

Emissions from flares typical of those found at oil-field battery sites in Alberta, Canada, were investigated to determine the degree to which the flared gases were burned and to characterize the products of combustion in the emissions. The study consisted of laboratory, pilot-scale, and field-scale investigations. Combustion of all hydrocarbon fuels in both laboratory and pilot-scale tests pro...

We report on the development and application of a broadband absorption spectrometer utilizing a pulsed supercontinuum laser light source and dispersion compensating fiber with a single-pass absorption path to obtain absolute methane mole fractions in a laminar nonpremixed CH(4)/air flame supported on a Wolfhard-Parker burner. The basic principle of supercontinuum broadband absorption spectrosco...

The combination of in situ X-ray absorption spectroscopy, X-ray diffraction and on-line catalytic data provided insight into the structure-performance relationship of a flame-made Pd/ZrO(2) catalyst during the total oxidation of methane: upon heating, a sudden reduction accompanied by sintering of the Pd-particles, leads to a significantly lower catalytic activity and a hysteresis during coolin...

Picosecond four-wave mixing experiments have been used to study collisions in a Na-seeded, premixed, methane-air flame. Population gratings are used to measure Na excited-state quenching collision rates, while polarization gratings are used to measure Na ground-state hyperfine coherence randomizing collision rates and overall Na diffusion rates, even though these processes are slower than the e...

The effects of channel width, wall temperature, and flow rate on the dynamics of non-premix flames in a mesoscale combustor were studied in methane and propane–air mixing layers. A flame street structure which consists of multiple triple flamelets in the mixing layer of the reactants was observed experimentally for the first time. Depending on the flow rate, it was found that there are two diff...

A stagnation-flow burner facility was used to study the catalytic surface reactions of premixed combustion systems at atmospheric pressure. The configuration serves as an important platform to investigate the interaction between homogeneous and heterogeneous reactions with independent control of the characteristic chemical and physical residence time scales. Methane/oxygen/nitrogen and propane/...

Experiments were conducted on monodisperse streams of small ( 100 m) methanol and ethanol droplets, injected perpendicularly to the axis of an axisymmetric methane diffusion flame. After crossing the methane flame, the droplets ignited and continued to burn outside of the “domain of influence” of the gaseous flame till they eventually extinguished. The extinction behavior was studied as a funct...

The effects of H2 enrichment on the propagation of laminar CH4–air triple flames in axisymmetric coflowing jets are numerically investigated. A comprehensive, time-dependent computational model, which employs a detailed description of chemistry and transport, is used to simulate the transient ignition and flame propagation phenomena. Flames are ignited in a jet-mixing layer far downstream of th...