Abstract It is not known if the thermodynamic behavior of some minerals and their synthetic analogues are quantitatively same. Olivine an important rock-forming substitutional solid solution consisting two end-members forsterite, Mg2SiO4, fayalite, Fe2SiO4. We undertook first heat capacity, CP, measurements on natural olivines between 2 300 K; nearly end-member fayalite a forsterite-rich crysta...