Applying density functional theory (DFT) calculations, we have designed fullerenes (C20, C24, C26, C28, C30, C36, C60 and C70) intercalated phthalocyanine covalent organic frameworks (Cn-Pc-PBBA COFs). First principles molecular dynamics (MD) simulations showed that the structures of Cn-Pc-PBBA COFs are stable at room temperature and even at higher temperature (500 K). The interlayer distance o...

Native population of raspberry fruits (Rubus spp) were treated with Methyl Jasmonate (MJ) fumigation and were assayed for the antioxidant capacity, total anthocyanins and postharvest quality after 7 days storage at 4?C. The result of experiment revealed that berries treated with methyl jasmonate (MJ) showed higher antioxidant capacity and total anthocyanins compared to the controled ones (non...

abstract antioxidant capacity and quality of fruits usually changed during storage. in the current study, the changes of antioxidant capacity and postharvest quality of two blood (pigmented) orange cultivars (‘tarocco’ and ‘morro’) and ‘thompson navel’ orange, after 60 days storage at 7ºc and 90 rh% was investigated. during fruit storage weight loss, tss, ta, tss/ta, vitamin c, total phenol, an...

The high theoretical gravimetric capacity of the Li-S battery system makes it an attractive candidate for numerous energy storage applications. In practice, cell performance is plagued by low practical capacity and poor cycling. In an effort to explore the mechanism of the discharge with the goal of better understanding performance, we examine the Li-S phase diagram using computational techniqu...

Here, we demonstrate a strategy to produce high areal loading and areal capacity sulfur cathodes by using vapor-phase infiltration of low-density carbon nanotube (CNT) foams preformed by solution processing and freeze-drying. Vapor-phase capillary infiltration of sulfur into preformed and binder-free low-density CNT foams leads to a mass loading of ∼79 wt % arising from interior filling and coa...

Abstract Physisorption of hydrogen in nanoporous materials offers an efficient and competitive alternative for storage. At low temperatures (e.g. 77 K) moderate pressures (below 100 bar) molecular H 2 adsorbs reversibly, with very fast kinetics, at high density on the inner surfaces such as zeolites, activated carbons metal–organic frameworks (MOFs). This review, by experts Task 40 ‘Energy Stor...

We determine the saturation storage density for hydrogen on several metal−organic framework (MOF) and covalent−organic framework (COF) materials by spillover. We use density functional theory on periodic frameworks to achieve reliable and accurate predictions for these materials. We find that one hydrogen can be stored at each C atom of the linker, and an additional H for each CO2 group. For IR...

Advanced energy-storage systems are critically important for meeting the ever-increasing demand for applications from portable electronics to all-electric vehicles, and recently for applications in the grid for storing energy from fluctuating renewable sources, such as wind or solar energy. Lithium-ion batteries (LIBs) have received worldwide attention as a top performing energy-storage system....

Humanity produces data at exponential rates, creating a growing demand for better storage devices. DNA molecules are an attractive medium to store digital information due to their durability and high information density. Recent studies have made large strides in developing DNA storage schemes by exploiting the advent of massive parallel synthesis of DNA oligos and the high throughput of sequenc...