with the aim of recognizing the steric effects on the silylenic r2c6h6si structures, dft calculationsare carried out on 8 structures of r2c6h6si (where r is hydrogen (h), methyl (me), isopropyl (i-pro),and tert-butyl (tert-bu)). these species are at either triplet (t) or singlet (s) states. singlet–tripletenergy separations ( me (20.32) > t-bu (15.92).all singlet states of r2c6h6si, are more st...

A 17-year-old boy presented with intermittent cough, fatigue, and fever. Computed tomography showed a mediastinal mass and hypodense splenic lesions. Biopsy of the mediastinal mass revealed numerous follicles with atrophic germinal centers and “onion skin”-like expanded mantles penetrated by hyalinized vessels, morphologically consistent with hyaline vascular Castleman disease (CD) (panel A, he...

With the aim of recognizing the steric effects on the silylenic R2C6H6Si structures, DFT calculationsare carried out on 8 structures of R2C6H6Si (where R is hydrogen (H), methyl (Me), isopropyl (i-pro),and tert-butyl (tert-Bu)). These species are at either triplet (t) or singlet (s) states. Singlet–tripletenergy separations ( Me (20.32) > t-Bu (15.92).all singlet states of R2C6H6Si, are more st...

In this paper, differences of infrared spectra hydrate formation inhibitors thermodynamic and kinetic action types were investigated. The method was proposed for determining the type a inhibitor by its spectrum. relevance is due to expressiveness in comparison with testing laboratory tests. It use Fourier transform spectrometry. allows us obtain data on molecular intermolecular interactions sub...

Using a visible beam to probe the thermal effect induced by infrared absorption, mid-infrared photothermal (MIP) microscopy allows bond-selective chemical imaging at submicron spatial resolution. Current MIP microscopes cannot reach the high wavenumber region due to the limited tunability of the existing quantum cascade laser source. We extend the spectral range of MIP microscopy by difference ...

The hardness was found to be lower (by ;10 in Rockwell H scale) and the volume electrical resistivity was found to be higher (about doubled) at the edge (up to a depth of ;5 cm for curing at 100% relative humidity) than at the center of a cement mortar specimen prior to loading. This is attributed to the faster drying at the edge and the resulting poorer bond between cement paste and sand at th...

Hexakis(dimethyl sulfoxide)scandium(III) iodide, [Sc(OS(CH(3))(2))(6)]I(3) contains centrosymmetric hexasolvated scandium(III) ions with an Sc-O bond distance of 2.069(3) angstroms. EXAFS spectra yield a mean Sc-O bond distance of 2.09(1) angstroms for solvated scandium(III) ions in dimethyl sulfoxide solution, consistent with six-coordination. Raman and infrared absorption spectra have been re...

H (Rydberg) atom photofragment translational spectroscopy and ab initio electronic structure calculations are used to explore ways in which ring substituents affect the photofragmentation dynamics of gas phase pyrroles. S1 ← S0 (σ* ← π) excitation in bare pyrrole is electric dipole forbidden but gains transition probability by vibronic mixing with higher electronic states. The S1 state is disso...