An automated gas chromatograph with sample pre-concentration for the measurement of peroxyacetylnitrate (PAN) was constructed with a minimum detection limit below 1 pptv. This instrument was deployed at the British Antarctic Survey’s Halley Research Station, Antarctica (75.6 S, 26.6 W) as part of the CHABLIS (Chemistry of the Antarctic Boundary Layer and the Interface with Snow) campaign. Hourl...