A comparative research has been developed for acidity and stability constants of M(Glu), M(Asp) and M(Ttr) complexes, which have been determined by potentiometric pH titration. Depending on metal ion-binding properties, vital differences in building complex were observed. The present study indicates that in M(Ttr) complexes, metal ions are arranged to the carboxyl groups, but in M(Glu) and M(As...

A method has been developed for determining of heavy metal ions by field-amplified sample injection capillary electrophoresis with contactless conductivity detection. The effects of the 2-N-morpholinoethanesulfonic acid/histidine (MES/His) concentration in the sample matrix, the injection time and organic additives on the enrichment factor were studied. The results showed that MES/His with a lo...

Background and purpose: The discharge of toxic heavy metal ions into the environment is a serious pollution problem. Heavy metal ions pose adverse toxic risks to human health at very low concentrations. The aim of this paper is the adsorption potential of chitosan (CS) in the removal of Hg(II) and Cd(II) ions from aqueous solution. Materials and Methods: This study was conducted in laboratory s...

The effect of heavy metal ions (Cd, Cr 3+ , Cu 2 , Ni, Pb 2+ and Zn) on the growth and germination of conidia of the aphid pathogenic fungus Pandora neoaphidis was studied. The metal ions were added into the culture medium in three concentrations: A – concentration corresponding to the mean content of that metal in Polish soils, B – concentration 10-times higher and C – 100-times higher than th...

A series of adsorption tests were conducted to analyze the sorption capacity of attapulgite. Ions such as cobalt, nickel, lead and cadmium were adsorbed from waste solutions onto attapulgite surface. Adsorption depletion tests were performed as a function of solid to liquid ratio, conditioning time, heavy metal ion concentration, and pH to identify the mode and extent of interactions in the sys...

We present the use of hydrazone dynamic combinatorial libraries (DCLs) to identify macrocyclic receptors that are selective for alkaline earth metal ions over alkali metal ions. In particular, the toxic heavy metal ions Sr(2+) and Ba(2+) induce characteristic changes in the DCLs. Four macrocycles were isolated and characterised by LCMS, HRMS, NMR and X-ray crystallography; binding studies by UV...

Heavy metal remediation of aqueous streams is of special concern due to recalcitrant and persistency of heavy metals in environment. Conventional treatment technologies for the removal of these toxic heavy metals are not economical and further generate huge quantity of toxic chemical sludge. Biosorption is emerging as a potential alternative to the existing conventional technologies for the rem...

The metallothioneins are a family of heavy-metal binding proteins of low molecular weight. They function in the regulation of trace metal metabolism and in the protection against toxic heavy metal ions. In man, the metallothioneins are encoded by at least 10-12 genes separated into two groups, MT-I and MT-II. To understand the genomic organization of these genes and their involvement in heredit...

The study of heavy metal speciation is of interest for the evaluation of their ecotoxicological risk. Free heavy metal ion concentrations of Cu2+, Zn2+, Ni2+ and Cd2+ were studied at different soil to soil solution ratio (SSR) to discuss metal bioavailability and toxicity in circumstance. The samples were collected from two farmed soils, impacted by a cadmium rich zinc deposit, Guizhou, China. ...

keep in mind the importance of cadmium, cobalt and nickel ions as environmentally and economically strategic heavy metals, the application of two acidic extractants, named bis(2-diethylhexyl)phosphoric acid (dehpa) and 2-thenoyltrifluoroacetone (htta), was assessed for the extraction-recovery of these ions from leached solution of spent rechargeable ni-cd batteries. the conditions for leaching ...