In this study, MIL-101(Fe), MIL-101(Fe,Cu), and graphene oxide (GO)/MIL-101(Fe,Cu) were synthesized to compose a novel sorbent. The adsorption properties of these three MOF-based composites compared toward the removal phosphate. Furthermore, influencing factors including time, pH, temperature, initial concentration on capacity phosphate materials as well reusability material discussed. structur...

Constructing functional forms and their corresponding force field parameters for the metal-linker interface of metal-organic frameworks is challenging. We propose fitting these parameters on the elastic tensor, computed from ab initio density functional theory calculations. The advantage of this top-down approach is that it becomes evident if functional forms are missing when components of the ...

We have purified human coagulation Factor V 6,000fold to homogeneity from citrated plasma using polyethylene glycol 6000 precipitation, adsorption of Factor V to barium citrate, DEAE-Sepharose chromatography, and gel filtration on Ultrogel AcA 34 (yield 21%). Human Factor V is a single polypeptide chain before and after disulfide bond reduction with an apparent M, = 335,000 as determined by ele...

The inhibitive action of alkali extract human hair extract (Bio waste) against the corrosion of mild steel (98.58%) in solutions of nitric acid has been studied using potentiodynamic polarization and electrochemical impedance spectroscopy (EIS). At inhibitor concentration range (0.004 % v/ v to 0.1% v/v) in 0.3 M HNO3acid, the results showed that these compounds suppressed both cathodic and ano...

Spontaneously adsorbed monolayers of [Co(ttp-CH2-SH)2](PF6 ) 2 have been formed on platinum microelectrodes by exposure to micromolar solutions of the complex in 0.1 M TBABF4 in acetonitrile, ttp-CH2-SH is 4'-(p-(thiolmethyl)-phenyl)-2,2':6',2''terpyridine. Resonance Raman spectroscopy on roughened polycrystalline platinum macro electrodes show that the molecule undergoes adsorption by sulphur ...

effects of temperature and percentage of organic modifier were studied on retention and selectivity in rp-hplc using solvation parameter model. the system constants were determined by multiple linear regression analysis from experimental values in the retention factor for a group of different solutes with known descriptors by computer using the program spss/pc. the experimental results showed t...

This study reports on the first example, to our knowledge, of the usefulness of an ultrasound (US)-irradiation during an enzyme adsorption step, for enhancing the performance of a redox-enzyme-based amperometric biosensor. Horseradish peroxidase (HRP) and thionine (Th) were coadsorbed from a mixed aqueous solution of HRP and Th onto a carbon-felt (CF) under US-irradiation for 5 min with an ultr...