The reduction of tungsten hexachloride with lead powder was investigated by differential scanning calorimetry (DSC) combined with X-ray diffraction (XRD) studies. Intermediate compounds along the way of the reduction of W6+ to W2+ were detected, prepared by solid-state synthesis, and structurally characterized by X-ray diffraction techniques. Five new compounds, namely Pb0.5WCl6, PbW2Cl10, Pb1....

nicr2o4 normal spinel nanostructures were prepared via hydrothermal treatment at 180 °c for 12 h in the presence of cetyltrimethylammonium bromide (ctab), sodium dodecyl sulphate (sds) and poly vinylpyrrolidone-25000 (pvp-25000) as capping agents and subsequent calcination process at 500 °c for 3 h . in this method, [ni(en)2(h2o)2](no3)2 and [cr(en)3]cl3.3h2o used as precursors and not utilized...

in a hydrothermal route devoted for synthesis of ca10(po4)6(oh)2 (ha) nanostructures, morphology can be controlled by experimental condition to form magical ha or nanostructured nanoparticles. in an intermediate condition, a novel nanostructure namely rose-like bundle of ha rod-likes was found, which is different from known ha nanostructures. the chemical synthesis of nanopowders under hydrothe...

Nanocrystalline SrAl2Si2O8 :Eu2+ phosphor layers were coated on nonaggregated, monodisperse and spherical SiO2 particles using a hydrothermal homogeneous precipitation. After annealing at 1100 °C, core-shell SiO2@SrAl2Si2O8 :Eu2+ particles were obtained. They were characterized with x-ray diffraction (XRD), scanning electron microscopy, transmission electron microscopy and photoluminescence tec...

calcium fluoride nanoparticles with special amount of cerium ion (%1) were synthesized by coprecipitation. fourier transforms infrared spectroscopy (ftir), x-ray diffraction (xrd), absorption and photoluminescence (pl) from caf2ce nanoparticles has been investigated. ftir spectra reveal that there are some amounts of oh, no3 and other organic functional groups on the particle surfaces before th...

In the present paper, ZnO nanorods with the mean size of 50 nm× 250 nm were successfully synthesized via a hydrothermal synthesis route in the presence of cetyltrimethylammonium bromide (CTAB). ZnCl2 and KOH were used as the starting materials and zinc oxide nanorods were obtained at 120 ◦C for 5 h. The product was characterized by means of X-ray powder diffraction (XRD), transmission electron ...

Nanocomposite materials of the Au nanoparticles (Au/PDDA-G) and the bimetallic PtAu nanoparticles on poly-(diallyldimethylammonium chloride) (PDDA)-modified graphene sheets (PtAu/PDDA-G) were prepared with hydrothermal method at 90 °C for 24 h. The composite materials Au/PDDA-G and PtAu/PDDA-G were evaluated by transmission electron microscopy (TEM), X-ray diffraction (XRD), X-ray photoelectron...

molecular sieves and zeolites are materials whose crystalline frameworks form nanometer or subnanometer pores. a variety of different crystal structures are known having a range of pore sizes. because the pore sizes are usually smaller than 2 nm, they are classified as microporous materials. synthesis of microporous materials is usually conducted by the high temperature treatment (80-200 °c) of...

The present research reports fabrication of nanoand submicrometer-sized BiFeO3 (BFO) powders from bismuth nitrate and iron chloride by a simple hydrothermal method at 180°C for 16 h in the presence of various MOH mineralizers (M = K, Na and Li). The final products were characterized by X-ray powder diffraction (XRD) and high-resolution transmission electron microscope (HR-TEM). Alkaline mineral...

Single-crystalline V2O5 xH2O nanorings and microloops were chemically assembled via an ion-induced chemical spinning route in the designed hydrothermal system. The morphology and structure of products were investigated by means of scanning electron microscopy (SEM) and transmission electron microscopy (TEM). X-ray powder diffraction (XRD) measurement, energydispersive X-ray spectroscopy (EDS) m...