We describe the facile synthesis of several two-dimensional covalent-organic frameworks (2D COFs) as films by vapor-assisted conversion at room temperature. High-quality films of benzodithiophene-containing BDT-COF and COF-5 with tunable thickness were synthesized under different conditions on various substrates. BDT-COF films of several micrometer thickness exhibit mesoporosity as well as text...

The one-dimensional (1D) mesoporous and interconnected nanoparticles (NPs) enriched composite Co3O4-CuO nanofibers (NFs) in the ratio Co:Cu = 1/4 (Co3O4-CuO NFs) composite have been synthesized by electrospinning and calcination of mixed polymeric template. Not merely the mesoporous composite Co3O4-CuO NFs but also single mesoporous Co3O4 NFs and CuO NFs have been produced for comparison. The c...

Metal-Organic Frameworks (MOFs) are extensively used in different applications, including heterogeneous catalysis given the fact that practically any center can be designed on demand and is accessible for reactants. Just like other microporous catalysts, limited diffusion of reactants products an endemic drawback also MOFs. To face it, use nanocrystalline MOFs a proven alternative, which additi...

A systematic and detailed analysis of adsorption and diffusion properties of xylene isomers over Beta zeolites with different mesoporosity was conducted. Adsorption isotherms of xylene isomers over microporous and mesoporous Beta zeolites through gravimetric methods were applied to investigate the impact of mesopores inside Beta zeolites on the adsorption properties of xylene isomers in the pre...

Here, several ?-Fe2O3/SiO2 nanocomposite microspheres were synthesized, characterized and tested as magnetically separable heterogeneous catalysts in an advanced oxidation process. A strong relation between the structure activity of these materials was evidenced. Two parameters, including porosity silica support doping material with Fe3+ ions addition to ?-Fe2O3 nanoparticles, investigated. The...