We successfully immobilized metalloporphyrins (MeP) in mesoporous silica coating magnetite spheres. In this sense, we prepared two different classes of core@shell supports, which comprise aligned (Fe3O4-AM-MeP, MeP=FeP or MnP) and non-aligned (Fe3O4-NM-MeP, MeP=FeP or MnP) mesoporous magnetic structures. X-ray diffractometry and energy dispersive X-ray spectroscopy confirmed the mesoporous natu...

The detailed synthesis of highly hydrophobic average pore benzene-bridged hybrid mesoporous silicas under an acidic medium is described. With the use of a 1,4-bis(triethoxysilane)benzene silsesquioxane precursor and biodegradable alkyl polyoxyethylene (Brij-56 or Brij-76) nonionic surfactant oligomers as supramolecular templates, no molecular scale periodicity was observed. The well-defined mes...

Metal-containing mesoporous starches have been synthesized using a simple and efficient microwave-assisted methodology followed by metal impregnation in the porous gel network. Final materials exhibited surface areas >60 m² g-1, being essentially mesoporous with pore sizes in the 10-15 nm range with some developed inter-particular mesoporosity. These materials characterized by several technique...

We have measured atomic pair distribution functions of novel mesoporous metal oxides, α-Fe2O3 and Cr2O3. These have an ordered pore mosaic as well as crystalline structure within the pore walls, making them an interesting class of materials to characterise. Comparison of "bulk" and mesoporous data sets has allowed an estimate of long range structural coherence to be derived; ≈125 Å and ≈290 Å f...

Poly(alkylene oxide)-type block copolymers have been recently shown to be particularly versatile as structure-directing agents for the preparation of ordered large-pore mesoporous silica materials. In principle, the structure direction is achieved through the formation of periodic supramolecular self-assemblies between the polymeric surfactants and a silica source in the aqueous solution. The o...

Cerium-rich metal oxide materials have recently emerged as promising candidates for the photocatalytic oxygen evolution reaction (OER). In this article, we report the synthesis of ordered mesoporous CuO/CeO₂ composite frameworks with different contents of copper(II) oxide and demonstrate their activity for photocatalytic O₂ production via UV-Vis light-driven oxidation of water. Mesoporous CuO/C...

To use mesoporous silicas as low-k materials, the pore entrances must be really small to avoid diffusion of metals that can increase the dielectric constant of the low-k dielectric. In this paper we present a new method to narrow the pores of mesoporous materials through grafting of a cyclic-bridged organosilane precursor. As mesoporous material, the well-studied MCM-41 powder was selected to a...

In this paper, we report a soft route leading to small gold nanoparticles confined within the framework of 2D-hexagonal mesoporous SH-functionalised silicas. For that purpose, a hydrophilic bis-silylated precursor containing a disulfide unit was prepared. Framework-functionalised materials were obtained in one step by the ‘‘direct synthesis’’ method which consists of a co-hydrolysis and polycon...

Micro/mesoporous zeolitic composites (MZCs) represent an important class of hierarchical zeolitic materials that have attracted increasing attention in recent years. By introducing an additional mesoporous phase interconnected with the microporosity of zeolites, a hierarchical porous system of MZCs is formed which facilitates molecular transport while preserving the intrinsic catalytic properti...

Mesoporous materials offer several unique properties when incorporated in microelectromechanical systems (MEMS) including low density, thermal insulation and the ability to carry out rapid etching. This paper describes the development of two mesoporous thin film materials for MEMS structures, an organically modified silicate and crystalline TiO2. The morphologies of the mesoporous thin films ar...