In this chapter we explore the possibility that within Optimality Theory, a single syntactic grammar directly yields not only competence theoretic results on the grammatical distributions of elements, but also performance theoretic results on relative preferences when processing sentences with various syntactic ambiguities. Whereas the competence theory applies the grammar at the level of an en...

The use of olefin metathesis as a construction tool for multimetallic salen-based structures is described. The approach involves mono- and diallyl-functionalized metallosalen complexes that can be directly coupled by metathesis leading to dimetallic species or mixtures of linear and cyclic oligomers. The metathesis of bis-allyl Ni(salen) complexes has been studied in detail. At high concentrati...

Density functional theory calculations were used to predict the behaviour of a potential novel architecture of olefin metathesis catalysts, in which one of the neutral ligands of classical Ru-based catalysts, e.g. a phosphine or an N-heterocyclic carbene, is replaced by an alkylidene group. Introduction of a second alkylidene ligand favors dissociation of the remaining phosphine and the overall...

In this chapter, we explore the implications of Optimality Theory (OT) for speech-language pathology.. But at the time of writing, the most accessible readings in OT for the speech-language pathologist are to be found in Bernhardt, Gilbert, and Ingram (1996). The first part of the chapter outlines major aspects of OT, and the second part discusses application of this theory to phonological inte...

René Kager’s textbook is one of the first to cover Optimality Theory (OT), a declarative grammar framework that swiftly took over phonology after it was introduced by Prince, Smolensky, and McCarthy in 1993. OT reclaims traditional grammar’s ability to express surface generalizations (“syllables have onsets,” “no nasal+voiceless obstruent clusters”). Empirically, some surface generalizations ar...