A 1D heterogeneous reactor model accounting for interfacial and intra-particle gradients was developed to simulate the dehydration of 2,3-Butanediol (2,3-BDO) to 1,3-Butadiene (1,3-BD) and Methyl Ethyl Ketone (MEK) over an amorphous calcium phosphate (a-CP) catalyst in a pilot-scale fixed-bed reactor. The developed model was validated with experimental data in terms of a fluid temperature profi...

Fluctuations in concentration of organic vapors in gas streams that are treated by devices such as biofilters or oxidizers make it challenging to remove the vapors from the gas streams in an efficient and economic manner. Combining adsorption with concentration-controlled desorption provides an active buffer between the source of vapors and the control device for better control of concentration...

The main objective of this study is to improve the performance and cleaning up of diesel engine's exhaust by fumigating known quantity of methanol and methyl ethyl ketone individually using a custom made Electronic fuel injector controlled by a microprocessor. To control the emission from diesel engine and to improve performance, alternate fuel and in-cylinder control techniques are used. The e...

In the past forty years in Japan and Taiwan, many thermal explosions have been caused by methyl ethyl ketone peroxide (MEKPO) under the influence of external fire and others. Thermograms of commercialized MEKPO dimers were first screened by Differential Scanning Calorimetry (DSC) to determine the heat of decomposition and exothermic onset temperature. Thermal runaway phenomena were then thoroug...

Kinetics of Ru (III) catalyzed oxidation of aliphatic ketones such as acetone, ethyl methyl ketone, diethyl ketone, iso-butylmethyl ketone by N-bromosuccinimide in the presence of Hg(II) acetate have been studied in aqueous acid medium. The order of [N-bromosuccinimide] was found to be zero both in catalyzed as well as uncatalyzed reactions. However, the order of [ketone] changed from unity to ...

Abstract The fine chemical and pharmaceutical industries use large amounts of various organic solvents in their manufacturing processes. By reusing them, production costs can be significantly reduced. If we regenerate waste solvent mixtures, have the opportunity to reuse them process or other Our study illustrates an efficient regeneration using example a four-component mixture. Calculations we...

Propionicacidaemia is an inborn error of organic acid metabolism in which there is a defect in propionyl-CoA carboxylase activity, and a clinical picture of overwhelming illness very early in life which was originally described as ketotic hyperglycinaemia (Childs et al., 1961; Hommes et al., 1968; Hsia et al., 1970). These patients have large amounts of glycine in their blood and urine. They al...

The present study was aimed for the effects of exposure to multiple organic solvent vapors in comparison with single exposure to phenol. It included 20 workers exposed to phenol alone and 32 workers of combined exposure to phenol, benzene, toluene and methyl ethyl ketone. A control group of 30 subjects was also included. The levels of transaminases, total proteins, prothrombin time, bleeding ti...