In this Letter, we experimentally show that the room temperature ferromagnetism in the Mn-Zn-O system recently observed is associated with the coexistence of Mn(3+) and Mn(4+) via a double-exchange mechanism. The presence of the ZnO around MnO(2) modifies the kinetics of MnO(2)-->Mn(2)O(3) reduction and favors the coexistence of both Mn oxidation states. The ferromagnetic phase is associated wi...

Three kinds of silicate phosphor thin films, emitting in the red-green-blue (RGB) primary colors, were fabricated by pulsed laser deposition: manganese and lead doped calcium silicate (CaSiO3:MnPb) for red color, manganese doped zinc silicate (Zn2SiO4:Mn) for green color, and cerium doped yttrium silicate (Y2SiO5:Ce) for blue color. A good correlation was found between photoluminescence intensi...

Recent efforts on doping ZnO films for charge and spin functionality are reviewed, focusing on chemical doping for charge and spin device formation. Discussion includes the behavior of phosphorus as an acceptor and magnetism in transition metal-doped ZnO. Evidence for p-type behavior in phosphorus-doped (Zn,Mg)O grown by pulsed laser deposition is presented. The magnetic properties of ZnO co-do...

A Sb-doped ZnO microrod array was fabricated on an Al-doped ZnO thin film by electrodeposition. Strong violet luminescence, originated from free electron-to-acceptor level transitions, was identified by temperature-dependent photoluminescence measurements. This acceptor-related transition was attributed to substitution of Sb dopants for Zn sites, instead of O sites, to form a complex with two Z...

in this paper, zno thin film is deposited on slide glass substrate using the sol-gel process. presenting well-defined orientation of zno thin films nanostructure were obtained by dip coating of zinc acetate dihydrate, monoethanolamine (mea), de-ionized water and isopropanol alcohol. the annealed zno thin films were transparent ca 85-90% in visible range with an absorption edges at about 375 nm....

High-Performance Thin-Film Solar Cells In article number 2207966, Jung-Je Woo, Jin Hyeok Kim, Hyeong-Jin and co-workers demonstrate the Mg- Ga-doped ZnO/Li-doped graphene oxide transparent electrode (TE)/electron-transporting layer (ETL) combination in thin-film solar cells. This newly designed TE/ETL not only increases electron collection rate but also suppresses open-circuit voltage deficit, ...

in this study, undoped zno and doped with fe and mn nanostructures were synthesized by hydrothermal method. the morphology of nanostructures was characterized by scanning electron microscope. the electrochemical response of the carbon paste electrode modified with nanoparticles of zno and also zno doped with fe and mn toward levodopa (l-dopa) was studied. studies of cyclic voltammetry using pro...

We report the synthesis and characterization of several sizes of Mn-doped ZnO nanocrystals, both in the free-standing and the capped particle forms. The sizes of these nanocrystals could be controlled by capping them with polyvinylpyrollidone under different synthesis conditions and were estimated by X-ray diffraction and transmission electron microscopy. The absorption properties of PVP-capped...

The geometric structures, electronic and magnetic properties of Mn-doped ZnO nanowires were investigated using density functional theory. The results indicated that all the calculated energy differences were negative, and the energy of the ground state was 0.229 eV lower than ferromagnetic coupling, which show higher stability in antiferromagnetic coupling. The calculated results indicated that...