A chemically modified electrode based on a chitosan-multiwall carbon nanotube (MWNT) coated glassy carbon electrode (GCE) is described, which exhibits an attractive ability to determine dopamine (DA) and ascorbic acid (AA) simultaneously. The modified electrode exhibited a high differential pulse voltammetry (DPV) current response to DA at 0.144 V and AA at -0.029 V (vs. SCE) in a 0.1 mol l(-1)...

Aryl-substituted tetraimine complexes related to Co(dmgBF(2))(2)(MeCN)(2) (dmg = dimethylglyoxime) were synthesized and are active for hydrogen evolution. Co(dmgBF(2))(2)(MeCN)(2) can be adsorbed to a glassy carbon electrode. The chemically modified electrode is active for hydrogen evolution in aqueous solution at pH < 4.5, with an overpotential of only 100 mV.

A simple and green chemistry protocol has been proposed based on the covalent anchoring of benzamide molecule on glassy carbon spheres through ball milling under solvent free condition. The modification proceeds through the formation of an amide bond between carboxylic group of glassy carbon spheres and the amino group of modifier molecule. The formation of covalent bond was ascertained using X...

Copper nanoparticles were fabricated by electro-reduction of CuSO4solution in the presence of cetyltrimethylammonium bromide (CTAB) cationic surfactant as an additive through potentiostatic method. The prepared copper nanoparticles were characterized by scanning electron microscopy (SEM) and electrochemical methods. The SEM images reveal that the nanoparticles with diameters at about 70 n...

The analysis of Cu(II) by anodic stripping voltammetry using a Nafion-modified glassy Carbon electrode incorporated with Cu-DPABA complex (DPABA is Methyl 3,5bis{bis-[(pyridin-2-yl)methyl]amino}methyl)benzoate ) (Cu-DPABA–NA/GCE) is described. Cu(II) was accumulated in Hac-NaAc buffer pH=4 at potential of -0.3 V (vs. Ag/AgCl ref. electrode) and then determined with SWASV. Under the optimum cond...

DNA was immobilized on glassy carbon electrodes to fabricate DNA-modified electrodes. The direct electron transfer of horse heart cytochrome c on DNA-modified glassy carbon electrode was achieved. A pair of well-defined redox peaks of cytochrome c appeared at Epc = -0.017 V and Epa = 0.009 V (vs. Ag/AgCl) in 10 mM phosphate buffer solution (pH 7.0) at a scan rate of 50 mV/s. The electron transf...

A glassy carbon electrode was modified with a copper(II) complex [Cu(Sal-β-Ala) (3,5-DMPz)2] (Sal = salicylaldehyde, β-Ala = β-alanine, 3,5-DMPz = 3,5-dimethylpyrazole) and single-walled carbon nanotubes (SWCNTs). The modified electrode was used to detect catechol (CT) and hydroquinone (HQ) and exhibited good electrocatalytic activities toward the oxidation of CT and HQ. The peak currents were ...

A glassy carbon electrode modified with ruthenium red and functionalized multi-walled carbon nanotube has been developed. The electrochemical response characteristics of the modified electrode toward epinephrine (EP) and acetaminophen (AC) was investigated by differential pulse voltammetry (DPV). Linear calibration plots were obtained over the range of 0.3 - 333.3 μM for both EP and AC with sen...

A simple and sensitive voltammetric method using in-situ bismuth film modified glassy carbon electrode (BiFGE) and Nafion-coated bismuth film modified glassy carbon electrode (NC-BiFGE) were used to determine the amount of lead(II) present in locally produced (at Kombolcha, 376 km North of Addis Ababa, Ethiopia) and imported cooking utensils and vegetable samples before and after cooking with t...

A sensitive and selective amperometric procedure, based on a glassy carbon electrode (GCE) modified with a thin multi-wall carbon nanotube (MWNT) film, for the determination of ascorbic acid (AA) was developed. The modified electrode showed excellent electrocatalytic activity towards the oxidation of AA. The oxidation potential of AA shifted negatively by as much as 460 mV to –18 mV (vs. SCE) a...