A novel carbon paste electrode modified with ionic liquid (n-hexyl-3-methylimidazolium hexafluoro phosphate) and magnetic core-shell manganese ferrite nanoparticles (MCSILCPE) was fabricated. The electrochemical study of the modified electrode, as well as its efficiency for electro-oxidation of tryptophan, is described. Cyclic voltammetry (CV), choronoamperometry (CHA) and square wave voltammet...

a carbon paste electrode modified with cobalt (ii) phthalocyanine (copc) was used as a sensitive potentiometric sensor for determination of ascorbic acid in aqueous solutions. the potential response of the electrode is a linear function of ascorbic acid concentration over the range 5 10 to 10 m (?1- 1800 µg ml ) with a nernstian slope of 56 mv at ph 7. the limit of detection was 0.2 µg ml ascor...

An analytical method has been described for the determination of mercury using a carbon paste electrode. Conditions for the preparation of the carbon paste electrode were optimized for low background current in order to use it for the determination of ultra trace levels of mercury. The carbon paste electrode was found to be a good electrode material for the determination of mercury. The optimiz...

In the present study, we investigate the potentiometric behavior of Cu2+ carbon paste electrodes based on two mercapto compounds 2-Ethylmino-5-Mercapto-1,3,4-Thiadiazole (EAMT) and 2-Acetylamino-5-mercapto-1,3,4-thiadiazole (AAMT) self-assembled on gold nano-paricle (GNP) as ionophore. Then, the results obtained from the modified electrodes are compared. The self-assembled ionophores exhibit a ...

A novel potentiometric, enantioselective membrane electrode based on graphite paste (graphite powder and paraffin oil), impregnated with 10–3 mol/L 2-hydroxy-3-trimethylammoniopropyl-β-cyclodextrin (as chloride salt) solution, has been constructed. The potentiometric, enantioselective membrane electrode can be used for the reliable assay of S-enalapril as raw material and from its pharmaceutica...

for the first time this study reported the success of using nanocrystalline hexagonal close-packed (hcp) nickel (ni) modified composite graphite (cg) electrode (hcp-nano ni/cg) for the electrocatalytic oxidation of glycerol in alkaline medium (0.1 m koh). the hcp-nano ni/cg electrode had an improve response and specificity on the electrocatalytic oxidation of glycerol over the bare cg. the elec...

A charge-transfer complex was modified on the graphite paste electrode for making a sensitive dissolved oxygen sensor. It was composed of copper with two ligands of phenanthroline and 1,2-dicyano-1,2-dithiolethane. Because of the low redox potential of the core ion and the pull and repulsive effect from the ligands, the redox of modified complex toke place under lower potential and it could sel...

Abstract A graphite paste electrode (GPE) was obtained by immobilizing graphene, and the electrocatalytic activity of fluorene (Flu) studied. The voltammetric behavior using graphene-modified GPE showed an irreversible redox reaction for Flu-ACN-KClO 4 . good linear correlation between anodic I C Flu ranged within 8–300 ng mL −1 Therefore, we recommend a facile synthesis modified impregnated wi...

A sodium dodecyl sulfate modified carbon paste electrode (SDS/CPE) was developed in this work based on the surface modification method. The modified electrode was prepared by immersing SDS/CPE in a nickel nitrate solution. This electrode showed a strong accumulation ability toward nickel ions. Then modified electrode was conditioned by potential recycling in a potential range of 0.2–0.8 V (vs. ...

The cyclic voltammetry of red PbO, -PbO2, -PbO2 and BaPbO3 was studied with two different types of electrodes in acidic and alkaline media. In one case, microcrystalline particles of lead oxides were mechanically immobilized on the surface of paraffin-impregnated graphite rod electrodes (PIGE), while in the other case, lead oxides were added to a paste of graphite and silicone oil. The overall ...