In environmental studies, we need to be able to predict the behaviour of contaminants in more or less complex physico-chemical contexts. The improvement of this prediction partly depends on establishing thermodynamic models that can describe the behaviour of these contaminants and, in particular, the sorption reactions on mineral surfaces. In this way, based on the mass action law, it is possib...

A biased Monte Carlo method for the insertion of water in dense clay–water systems is presented. The use of this algorithm results in a considerable increase of the success rate of insertion attempts. It allows us to compute water adsorption isotherms up to high water densities, where the conventional Monte Carlo scheme fails. The isotherms were calculated by a combination of molecular dynamics...

Sodium montmorillonite (Na-MMT) clay was modified with three different unnatural amino acids in order to design intercalated clay structures that may be used for bone biomaterials applications. Prior work on polymer-clay nanocomposites (PCNs) has indicated the effect of the appropriate choice of modifiers on enhancing properties of PCNs. Our X-ray diffraction results indicate an increase in the...

conducting polymers, because of their special properties, are used to introduce conductive polymeric composites. also, clays have recently been used for preparation of polymer composites with enhanced mechanical and thermal properties. the aim of this work is to study the synergetic effect of the co-presence of conducting polyaniline and montmorillonite in the polyethylene matrix. polyethylene ...

Metal ions present on smectite clay (montmorillonite) platelets have preferential reactivity towards peroxy/alkoxy groups during polyamide 6 (PA6) thermal decomposition. This changes the decomposition pathway and negatively affects the ignition response of PA6. To restrict these interfacial interactions, high-temperature-resistant polymers such as polyetherimide (PEI) and polyimide (PI) were us...

Intercalation products based on ionic exchange reaction between cationic dye methylene blue and Na-montmorillonite were prepared. Montmorillonite particles intercalated with methylene blue were characterized using X-ray diffraction, infrared spectroscopy, elemental and thermo-gravimetric analysis. The results showed that intercalation of dye molecules within the interlayer spaces of montmorillo...

Slow release formulations of the anionic herbicide sulfosulfuron (SFS) were prepared by incorporating it in micelles of an organic cation octadecyltrimethylammonium, which adsorb on the clay-mineral montmorillonite. The fraction of SFS adsorbed on the micelle-clay complex reached 98%, whereas for monomer-clay complexes, its adsorption was insignificant. Fluorescence studies showed surface conta...

ess as: P r visibl niversity 2013.11.0 Abstract In this study, laponite and montmorillonite clays were found to be able to decompose rhodamine B upon visible light irradiation (k > 420 nm). Very interestingly, it was found that rhodamine B on laponite underwent a stepwise N-deethylation and its decomposition was terminated once rhodamine 110, as a decomposition product, was formed, whereas the ...

The biodegradation of 14C-labeled phenanthrene in the presence of particles of montmorillonite and fulvic and humic acid–montmorillonite complexes was studied in a batch system. A mathematical model that takes into account the contribution to mineralization by the slowly desorbing compound was used to calculate the initial mineralization rates. Sorption of phenanthrene to the particles was dete...

-X-ray diffraction patterns of oriented films of montmorillonite containing enantiomeric tris(2,2'bipyridyl) ruthenium(II) chloride (Ru(bpy)22§ show a peak corresponding to basal spacings of approximately 27 ,~. This peak is absent from the X-ray patterns of montmorillonite films containing racemic cations. A basal spacing of 27 ,~ is consistent with the adsorption of 2 layers of the enantiomer...