Although Zn metal has been regarded as the most promising anode for aqueous batteries, its practical application is still restricted by side reactions and dendrite growth. Herein, an in-situ solid electrolyte interphase (SEI) film formed on interface of electrode/electrolyte during plating/stripping zinc anodes introducing trace amounts multidentate ligand sodium diethyldithiocarbamate (DDTC) a...

Copper(II) complexes of amino acids and peptides containing the chelating bis(imidazolyl) residues have been reviewed. The results reveal that bis(imidazolyl) analogues of these biomolecules are very effective ligands for metal binding. The nitrogen donor atoms of the chelating agent are the major metal binding sites under acidic conditions. In the presence of terminal amino group the multident...

A rigid dinitrile ligand was synthesized from two xanthene units condensed to a naphthalene-1,4,5,8diimide spacer. The rigidity and C shape of the ligand gave exclusively trans complexes with Pd(II), Ag(I), and Au(I). Evidence for complexation, coordination geometry, and stoichiometry was provided by a combination of 1H NMR, 19F NMR, and IR spectroscopy. The AuBF4 and PdCl2 complexes were shown...

The solution self-assembly of multidentate organothiols onto Au(111) was studied in situ using scanning probe nanolithography and time-lapse atomic force microscopy (AFM). Self-assembled monolayers (SAMs) prepared from dilute solutions of multidentate thiols were found to assemble slowly, requiring more than six hours to generate films. A clean gold substrate was first imaged in ethanolic media...

Fused pyridazines (1,2,3,6,7,8-hexahydro-cinnolino[5,4,3-cde]cinnoline, L and its 2,2,7,7-tetramethyl derivative, Me4L) are designed as rigid multidentate ligands for the construction of framework solids. In combination with copper(I) bromide (iodide) they provide excellent structural examples for predictive engineering and the possibilities for further fine-tuning of the framework architecture...

The discovery of the crown ethers stemmed from efforts to control the catalytic activity of vanadium and copper by complexation with multidentate ligands. The first crown ether, 2,3,11,12-dibenzo-1,4,7,10,13,16-hexaoxacyclo-octadeca-2,11-diene, was obtained in 0.4% yield during an attempt to prepare a phenolic ligand from catechol and bis(2-chloroethyl)ether. This compound, which complexed with...

A novel strategy for the separation of cadmium from base metals in chloride medium by anion exchange based on formation halo-complexes is presented this article. Instead using excess Br− or I− feed solution, resin fibre was first preloaded with Cd2+ adsorption Cl− solution. Thus, consumption iodide bromide minimized while promising high stability Cd2+. The thermodynamics and kinetics were studi...