3,3,6,6-tetramethyl-9-phenyl-3,4,6,7,9,10-hexahydroacridine-1,8-(2h,5h)-dione derivatives are synthesized by nano titanium dioxide as an efficient and reusable heterogeneous nano catalyst in a one pot multi component reaction. easy preparation and separation of catalyst, simply workup procedure, clean reaction and reusability of the catalyst up to 7 times without appreciable loss of its catalyt...

We have prepared and characterized a SnO2-decorated Pt-Sn(oxidized)/C cathode catalyst in a polymer electrolyte fuel cell (PEFC). Oxygen reduction reaction (ORR) performance of Pt/C (TEC10E50E) remained almost unchanged or even tended to reduce in repeated I-V load cycles, whereas the I-V load performance of the Pt-Sn(oxidized)/C prepared by controlled oxidation of a Pt-Sn alloy/C sample with t...

a simple, green and efficient method for synthesis of 2,4,5-trisubstituted imidazoles is described via three-component cyclocondensation of benzil or benzoin, aldehyde and ammonium acetate by using the nano sio2-supported ferric hydrogen sulfate (fhs/sio2), as a catalyst, under solvent-free conditions. the nano sio2 support and catalyst were characterized by x-ray diffraction (xrd), transmissio...

The effect of nanostructured supports on the activity of Rh catalysts was studied by comparing the catalytic performance of nanoand bulk-oxide supported Rh/ZnO, Rh/SiO2 and Rh/TiO2 systems in 1-hexene hydroformylation. The highest activity with 100% total conversion and 96% yield of aldehydes was obtained with the Rh/nano-ZnO catalyst. The Rh/nano-ZnO catalyst was found to be more stable and ac...

We propose a novel semiconductor compatible path for nano-graphene synthesis using precursors containing C-Br bonding and liquid catalyst. The unique combination of CBr4 as precursor and Ga as catalyst leads to efficient C precipitation at a synthesis temperature of 200 °C or lower. The non-wetting nature of liquid Ga on tested substrates limits nano-scale graphene to form on Ga droplets and su...

A supported trimetallic nano catalyst and a fixed bed catalytic process have been developed for the conversion of CO2 + H2O (in the form of steam) + 1% H2 to alcohol and propyne The mixture of CO2 +H2O and H2 is passed over Ru:Mn:Ni nano catalyst dispersed on a high surface area antase titanium dioxide catalyst support at 773 K and at atmospheric pressure with the gas space velocity of 6000-700...

Nano-dispersed Fe and Fe3O4 on reduced graphene oxide (Fe /Fe3O4-RGO) was prepared and characterized. The prepared Fe/Fe3O4-RGO was used as a magnetically separable Fenton-like catalyst and showed superior catalytic activity compared to Fe3O4-RGO and Fe3O4 as well as other Fenton-like catalysts for the removal of phenol. The Fe/Fe3O4-RGO achieved 100% removal efficiency for phenol within 30 min...

in this study, preparation of nano-sized gamma alumina with high specific surface area and high yield by thereaction between aluminum nitrate and sodium carbonate, without using any surfactant is reported. bohemite (aluminum oxyhydroxide) was prepared as a precursor by strict control of ph and reaction temperature. the gel produced was purified by washing followed by centrifugation. the specifi...

pyrano [2,3-d] pyrimidinone derivatives have received considerable interest from the pharmaceutical industry due to their wide range of interesting biological and therapeutic properties. nano al2o3 was found to be a highly efficient solid acid catalyst for the preparation of pyrano [2,3-d] pyrimidinone derivatives from the reaction of barbituric acid, aryl aldehyde and malononitrile. al2o3 nano...