نتایج جستجو برای: nipam polymer

تعداد نتایج: 93135  

2015
Yajing Guan Zhan Li Fei He Yutao Huang Wenjian Song Jin Hu

Chilling stress is an important constraint for maize seed establishment in the field. In this study, a type of "on-off" thermoresponsive coating agent containing poly (N-isopropylacrylamide-co-butylmethacrylate) (Abbr. P(NIPAm-co-BMA)) hydrogel was developed to improve the chilling tolerance of coated maize seed. The P(NIPAm-co-BMA) hydrogel was synthesized by free-radical polymerization of N-i...

2016
Thomas R. Wilks Rachel K. O’Reilly

A range of chemistries were explored for the efficient covalent conjugation of DNA to poly(N-isopropylacrylamide) (poly(NIPAM)) in organic solvents. Amide coupling and thiol-ene Michael addition were found to be ineffective for the synthesis of the desired products. However, the inverse electron-demand Diels-Alder (DAinv) reaction between tetrazine (Tz) and norbornene (Nb) was found to give DNA...

Journal: :Soft matter 2015
Lei Hou Peiyi Wu

The LCST-transitions of linear, well-defined polymers of N-isopropylacrylamide (NIPAM) and N-vinylcaprolactam (VCL), including a homopolymer mixture, diblock and statistical copolymers, in water are explored and compared by applying turbidity and FTIR measurements in combination with two-dimensional correlation spectroscopy (2Dcos). Only one transition is observed in all polymer systems, sugges...

2017
Mina Namvari Chandra S. Biswas Massimiliano Galluzzi Qiao Wang Bing Du Florian J. Stadler

Nanohybrids of graphene with water soluble polymer were synthesized using 'grafting from' method. GO, prepared by modified Hummers' method, was first reacted with sodium azide. Alkyne-terminated RAFT-CTA was synthesized by reaction of propargyl alcohol and S-1-dodecyl-S'-(α,α'-dimethyl-α"-acetic acid) trithiocarbonate. RAFT-CTA was grafted onto the GO sheets by facile click-reaction and subsequ...

Journal: :E3S web of conferences 2021

A group of crosslinked poly(N-isopropylacrylamide-co-acrylic acid) (P(NIPAM-co-AAc)) microgels with different amount acrylic acid (AAc) were synthesized by surfactant-free emulsion polymerization. The morphology and environmental sensitivity studied atomic force microscope (AFM). It was founded that the microgel particles monodispersed diameter dried latex about 800nm. Moreover, volume decrease...

2015
Ji Hoon Park Guo Zhe Tai Bo Keun Lee Seung Hun Park Ja Yong Jang Jung Soo Lee Jae Ho Kim Kwideok Park Ju Woong Jang Moon Suk Kim

BACKGROUND Hydrolyzed polyacrylonitrile (HPAN) has attracted much attention as a hydrogel for a broad range of biomedical applications. Therefore, in this study, we prepared HPAN derivatives with controllable compositions by the radical polymerization of acrylonitrile (AN), methacrylic acid (MAA) and N-isopropylacrylamide (NIPAM) monomers. RESULTS The prepared poly(AN-co-MAA-co-NIPAM) copolym...

Journal: :Chemical communications 2007
Hisao Koizumi Yumi Kimata Yasuhiro Shiraishi Takayuki Hirai

A polymeric photosensitizer, poly(NIPAM-co-RB), consisting of N-isopropylacrylamide and rose bengal units, demonstrates a temperature-controlled changeable oxygenation selectivity by singlet oxygen in water.

Journal: :International journal of pure and applied sciences 2022

In the present work, a new polymeric adsorbent; Poly(NIPAM-co-AN)/clay composite was prepared via in-situ polymerization. The copolymerization of N-isopropylacrylamide, acrylonitrile and calculated clay (about 5% w/w) were carried out at 65°C in presence 10 mL 1,4-dioxane using AIBN as an initiator. Characterization P(NIPAM-co-AN)/clay determined by FT-IR techniques. NIPAM-AN/clay has been used...

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