An application of large quantity of agricultural pesticides in rural area is a common practice in order to increase the productivity and yield, to protect the agricultural crop from pests and prevent products lost due to insect and bacterial contamination is a common practice. Resistance and mutation of some pests to chemicals are the causes of using larger quantity of pesticide in the developi...

This paper presents the study of the electrochemical oxidation of the insecticide Methidathion organophosphorous pesticide, using a boron-doped diamond (BDD) anode. The influence of current density, sodium chloride concentration, temperature and initial Methidathion concentration on the rate of COD abatement has been followed. The electrolyses were performed by using a solution composed of an e...

Different types of organophosphorous compounds constitute most potent pesticides. These chemicals attack the nervous system of living organisms causing death. Different organisms produce enzymes to degrade these chemicals. These enzymes are present in simple microorganisms from archaea, bacteria to complex eukaryotes like humans. A comparison of representative eight shortlisted enzymes involved...

The kinetic characteristic (Km) of cholinesterase from the crab Chasmagnathus granulata, the shrimp Farfantepenaeus paulensis and the fish Odontesthes bonaeriensis were compared and correlated with the anticholinesterasic effect of eserine (physostigmine). For the crustaceans, the estimated Km values were about 5-8 times higher than that estimated for the fish (0.04 mM). In the crab and the shr...

Phosphatase activities (cell-bounded phosphatases "BP" and freely dissolved phosphatases "D P") in water samples from a natural lake "Laguna Grande" (Antequera, Málaga, Spain) amended with 50 microg/ml of selected insecticides, herbicides and fungicide captan were studied under laboratory controlled conditions (temperature and agitation). Our data show that dissolved alkaline phosphatase was th...

Kumasi, Sekondi-Takoradi, and Accra are the major recipients of agricultural commodities or productions in Ghana, primarily due to their population and ready markets. To ensure food security, meet food demands, and mitigate the threats posed by pests and diseases, pesticides are used when cultivating vegetables and fruits in Ghana. The present study has been conducted to assess the concentratio...

In this study, the knowledge, attitudes and practices regarding pesticide use and the levels of exposure of farmers and residents to organophosphorous and/or carbamates pesticides were evaluated in two rural settings in Brazil. A questionnaire was completed by 112 farm workers aged ≥18 years. Almost all farmers acknowledged that pesticides were potentially harmful to their health (87.5%); howev...

A magnetic metal organic framework (MOF) composite was prepared. The composite was fabricated by incorporation of Fe3O4 nanoparticals with MOF. It was characterized and expected to offer a promising template for molecular immobilization and sensor fabrication because of its ordered structure and satisfying large specific surface area. The resulting composite was used to detect methyl parathion....

Organophosphorous compounds are widely used as biologically active agents. Two well-known pesticides belong to this group: dibutyl 1-butylamino-1cyclohexanephosphonate (DBBC) and 2,4-dichlorophenoxyacetic acid (2,4-D) [1, 2]. Their oxidative properties were studied and compared with those of diethyl 9-butylamino-9-fluorenephosphonate (DEBF). All these compounds also interact with biological and...

A comprehensive multi-residue method for the chromatographic separation and accurate mass identification of 101 pesticides and their degradation products using liquid chromatography/time-of-flight mass spectrometry (LC/TOF-MS) is reported here. Several classes of compounds belonging to different chemical families (triazines, organophosphorous, carbamates, phenylureas, neonicotinoids, etc.) were...