Recently, sulfur (S)-vacancies created on the basal plane of 2H-molybdenum disulfide (MoS2) using argon plasma exposure exhibited higher intrinsic activity for the electrochemical hydrogen evolution reaction than the edge sites and metallic 1T-phase of MoS2 catalysts. However, a more industrially viable alternative to the argon plasma desulfurization process is needed. In this work, we introduc...

Dibenzothiophene (DBT) is oxidized to the corresponding sulfoxide and sulfone in an emulsion system (W/O) composed of polyoxometalate anion [C(18)H(37)N(CH(3))3](5)[PV(2)Mo(10)O(40)] as both the surfactant and catalyst, using molecular oxygen as the oxidant and aldehyde as the sacrificial agent under mild conditions.

Abstract A novel CuWO 4 /SiO 2 heterojunction catalyst was successfully synthesized using a new sulfonamide derivative. The physical characteristics of the prepared samples were investigated by TGA, XRD, FTIR, SEM, UV, PL, and XPS. catalysts applied as nano photocatalyst for photooxidative desulfurization dibenzothiophene under visible light hydrogen peroxide an oxidant. photocatalytic oxidativ...

In the process of desulfurization, will produce a lot of the desulfurization liquid, desulphurization waste liquid containing high concentrations of salt, has the very good use value. If direct emissions will not only damage to the environment, but also wastes resources The reduction of the pollution resulting from desulfurization was studied. Rotary evaporator was employed to simulate vacuum c...

Tumor Necrosis Factor alpha (TNFα) is an inflammatory cytokine that plays a central role in the pathogenesis of chronic inflammatory disease. Here we describe the chemical synthesis of l-TNFα along with the mirror-image d-protein for use as a phage display target. The synthetic strategy utilized native chemical ligation and desulfurization to unite three peptide segments, followed by oxidative ...

A newly kind of spinosus loaded-heteropolyacid catalyst Fe3O4@MOF-PMoW (abbreviated as FeMP, M = Cr, Cu and Zr) has been obtained under one-pot method using the various magnetic MOF materials bases. Detailed characterizations have proved out structure, with stinging surface morphologies outside, which benefits for excellent desulfurization performance to larger contact area sulfur compounds muc...