lanthanide(iii) chloro complexes of 4[n-(4’-hydroxy-3’-methoxybenzalidene) amino] antipyrine semicarbazone (hmbaaps) (i) and 4[n-(3’,4’,5’-trimethoxybenzalidene) amino] antipyrine semicarbazone (tmbaaps) (ii) with the general composition lncl3.2l (ln = la, pr, nd, sm, gd, tb, dy or ho; l = hmbaaps or tmbaaps) are reported. all the complexes were synthesized in ethanolic medium and refluxed the ...

This works concerns cohomological support varieties of modules over commutative local rings. The main result is that the a derived tensor product pair differential graded Koszul complex join supports modules. generalizes, and gives another proof of, Dao third author dealing with Tor-independent complete intersection for complexes has broader applicability, including to exterior algebras

Abstract Dissipative optical solitons of particle-like structures can form soliton molecules with striking molecule-like interactions. However, the experimental investigation in ultrafast lasers is still largely confined to bound states only two and far from being explored for molecular complexes. Here, reconfigurable switching complexes originating binding soliton-pair was demonstrated around ...

The molecular hosts cyclodextrins form inclusion complexes with a wide variety of guests, resulting in complexes with various host:guest stoichiometries. In the case of a series of 19 1,4-naphthoquinolines as guests with either β- or γ-cyclodextrin studied using electrospray mass spectroscopy, in most cases only 1:1 complexes were observed, with 2:1 host:guest complexes observed in just 6 out o...

an injective map f : e(g) → {±1, ±2, · · · , ±q} is said to be an edge pair sum labeling of a graph g(p, q) if the induced vertex function f*: v (g) → z − {0} defined by f*(v) = (sigma e∈ev) f (e) is one-one, where ev denotes the set of edges in g that are incident with a vetex v and f*(v (g)) is either of the form {±k1, ±k2, · · · , ±kp/2} or {±k1, ±k2, · · · , ±k(p−1)/2} u {k(p+1)/2} accordin...

Sulfate adsorption on mineral surfaces is an important environmental chemical process. However, the structure of sulfate adsorption complexes has remained uncertain. In this study, we have determined the S−Fe distance of sulfate inner-sphere adsorption complexes on iron (Fe) oxyhydroxide (ferrihydrite) surfaces under air-dried conditions using sulfur K-edge extended X-ray absorption fine struct...

Six alkali metal tris(HMDS) magnesiate complexes (HMDS, 1,1,1,3,3,3,-hexamethyldisilazide) containing chiral diamine ligands have been prepared and characterised in both the solid- and solution-state. Four of the complexes have a solvent-separated ion pair composition of the form [{M·(chiral diamine)(2)}(+){Mg(HMDS)(3)}(-)] [M = Li for 1 and 3, Na for 2 and 4; chiral diamine = (-)-sparteine for...

Interacting RNA complexes are studied via bicellular maps using a filtration via their topological genus. Our main result is a new bijection for RNA-RNA interaction structures and a linear time uniform sampling algorithm for RNA complexes of fixed topological genus. The bijection allows to either reduce the topological genus of a bicellular map directly, or to lose connectivity by decomposing t...

Stable radicals 2-(6-uradinyl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazole-1-oxyl (Ur6IN) and 4-(p-tert-butylaminoxylphenyl)-2,6-di(propylamido)pyridine (DAPPN) form heterospin radical pair complexes due to complementary multi-point hydrogen-bonds.

A diastereomer pair of left- and right-handed square planar Pd(II) complexes was synthesized from a single chiral ligand as kinetic and thermodynamic products. Helicity inversion between the diastereomers occurred rapidly under thermal and microwave irradiation conditions.