The impact of land use change on regional climate can be substantial but also is variable in space and time. Past observational and modeling work suggests that in a ‘Mediterranean’ climate such as in California’s Central Valley, the impact of irrigated agriculture can be large in the dry season but negligible in the wet season due to seasonal variation in surface energy partitioning. Here we re...

Henry's Law constants (HLCs) of several common, subsurface hydrophobic organic pollutants (HOPs) including trichloroethylene (TCE), perchloroethylene (PCE) and benzene, toluene, ethylbenzene, and o-xylene (BTEX), were measured using a static headspace phase ratio (SHPR) method over a range of temperatures (35, 45, 55, and 65 degrees C) and experimentally and operationally relevant cyclodextrin ...

Atom-probe tomography, transmission electron-microscopy, x-ray diffraction, and firstprinciples calculations were employed to study the (i) compositional evolution of GPII-zones and "!-precipitates, and (ii) solute segregation at !-Al/"!-interfaces in Al-4 wt. % Cu alloys. GPII zones are observed for aging at 438 K for 8 h, whereas higher aging temperatures, 463 K for 8 h and 533 K for 4 h, rev...

The temperature dependence of the static contact angle could a priori be predicted by using surface tension partitioning. An original model based on transition state theory is also introduced. This considers thermocapillary fluctuations droplet near triple line and self-affine pinning this against solid substrate modeled with pseudo-periodic distribution adsorption sites. was studied for repres...

Liquid-ordered (Lo) and liquid-disordered (Ld) phase coexistence has been suggested to partition the plasma membrane of biological cells into lateral compartments, allowing for enrichment or depletion of functionally relevant molecules. This dynamic partitioning might be involved in fine-tuning cellular signaling fidelity through coupling to the plasma membrane protein and lipid composition. In...

This study examines the sensitivity in predicted levels of atmospheric organic particulate matter (M(o), microg m(-3)) as those levels may potentially be affected by changes in relative humidity and temperature. In a given system, for each partitioning compound, f(g) and f(p) represent the gaseous and particulate fractions (f(g) + f(p) = 1). Sensitivity in the M(o) levels becomes dampened as th...

We address questions posed by experiments that show small-chain alcohols reduce the miscibility transition temperature when added to giant plasma membrane vesicles (GPMVs), but increase that temperature when added to giant unilamellar vesicles. In giant unilamellar vesicles the change in temperature displays a definite minimum, between decanol and tetradecanol, as a function of alcohol chain le...