The four cupferronate ions in the dinuclear title compound, [Pb(2)(C(6)H(5)N(2)O(2))(4)], O,O'-chelate to the two Pb(II) atoms; two of the four nitroso O atoms are also involved in bridging. The geometry of both five-coordinate Pb(II)atoms is distorted Ψ-octa-hedral; if another two longer inter-molecular Pb⋯O inter-actions [at 2.955 (1) and 3.099 (1) Å] are considered, the geometry is a distort...

The effect of Pb(2+) ions on the Na(+),K(+)-ATPase was investigated in detail by means of steady-state fluorescence spectroscopy. Experiments were performed by using the electrochromic styryl dye RH421. It is shown that Pb(2+) ions can bind reversibly to the protein and do not affect the Na(+) and K(+) binding affinities in the E(1) and P-E(2) conformations of the enzyme. The pH titrations indi...

environmental contamination by toxic metals is a serious problem due to their extreme toxicity towards aquatic life and humans. biosorption is an alternative technology to conventional processes for the removal of metals. biosorption of pb(ii) ions on the lichen biomass of cladonia rangiformis hoffm. is presented in this research. batch experiments were conducted to study the biosorption prope...

In situ immobilization of poly[N-(4-carboxyphenyl)methacrylamide] has been performed on silica gel surface. Infrared (IR) and mass spectroscopies as well as thermogravimetry (TG) analysis have been used to elucidate the structure of immobilized polymer. An adsorption capacity of the synthesized composite towards Cu(II), Pb(II), Mn(II), Fe(III), Co(II), and Ni(II) ions has been estimated. Adsorp...

Poly[tris-(acetato-κ(2) O,O')(μ2-acetato-κ(3) O,O':O)tetra-kis-(μ3-acetato-κ(4) O,O':O:O')bis-(benzene-1,2-di-amine-κN)tetra-lead(II)], [Pb4(CH3COO)8(C6H8N2)2] n , (I), poly[(acetato-κ(2) O,O')(μ3-acetato-κ(4) O,O':O:O')(4-chloro-benzene-1,2-diamine-κN)lead(II)], [Pb(CH3COO)2(C6H7ClN2)] n , (II), and poly[(κ(2) O,O')(μ3-acetato-κ(4) O,O':O:O')(3,4-di-amino-benzo-nitrile-κN)lead(II)], [Pb(CH3COO...

In the title structure, [Pb(C(5)H(3)N(2)O(2))(2)](n), the Pb(II) ion is six-coordinated by two pyridazine-3-carboxyl-ate ligands via N and O atoms, with the carboxyl-ato O atoms acting as bidentate and bridging adjacent Pb(II) ions, giving rise to catenated mol-ecular ribbons propagating along the a-axis direction. The ribbons are connected by C-H⋯O hydrogen bonds and van der Waals inter-actions.

In the presented study, CuO-CoO-MnO/SiO2 nanocomposite was synthesis by Cu(II), Co(II), Mn(II), with 1:1:1 mole ratio and Tetraethyl orthosilicate. azo–azomethine 1-(3-imino-4-hydroxophenylazo-4-nitrobenzene)-4-methyl phenol (L) was synthesized and used as a ligand for capturing the metal ions. Also, 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide was applied as the i...

In this study, the novel surface ion-imprinted polymer (IIP) particles were prepared and applied as a electrode modifier in stripping voltammetric detection of lead(II) ion. A carbon paste electrode (CPE) modified with IIP nanoparticles and multi-walled carbon nanotubes (MWCNTs) was used for accumulation of toxic lead ions. Various factors that govern on electrochemical signals including carbon...

The present investigation describes the evaluation of feasibility of MWCNT-Fe3O4 nanocomposite toward adsorptive removal of Co(II) and Pb(II) from aqueous solution in batch mode. The Fe3O4–MWCNT hybrid was prepared using a simple one-pot strategy via in situ growth of Fe3O4 magnetic nanoparticles onto the surface of the MWCNT...

BACKGROUND The usage of polynuclear metal clusters as secondary building units (SBU's) in designing of metal organic frameworks (MOF's) is a field of current interest. These metal clusters have attracted a great deal of attention not only due to their interesting structural topologies but also due to promising physical and chemical properties. In this regard various d,f block (transition and la...