Persulfate-based in situ chemical oxidation (ISCO) has been increasingly used for the remediation of contaminated groundwater and soil. In recent years, there have numerous studies literature on all aspects activation persulfate contaminant removal at laboratory scale, including ways mechanisms activation, pathways degradation, factors associated with performance, methods characterizing process...

The influence of persulfate activation methods on polycyclic aromatic hydrocarbons (PAHs) degradation was investigated and included thermal, citrate chelated iron, and alkaline, and a hydrogen peroxide (H₂O₂)-persulfate binary mixture. Thermal activation (60 °C) resulted in the highest removal of PAHs (99.1%) and persulfate consumption during thermal activation varied (0.45-1.38 g/kg soil). Per...

Dicarboxylic acid ligands (malonate, succinate, and butylmalonate) stabilize 2 nm diameter IrO2 particles synthesized by hydrolysis of aqueous IrCl(6)2- solutions. Analogous monodentate (acetate) and tridentate (citrate) carboxylate ligands, as well as phosphonate and diphosphonate ligands, are less effective as stabilizers and lead to different degrees of nanoparticle aggregation, as evidenced...

This study focuses on development, characterization and validation of an artificial neural network (ANN) model for prediction of advanced oxidation of organics in water matrix. The different ANNs, based on multilayer perceptron (MLP) and radial basis function (RBF) methodologies, have been applied for modeling of the behavior of complex system; zero-valent iron activated persulfate oxidation (F...

The concentration of organic and inorganic carbon in seawater is of considerable interest. Some Total Organic Carbon (TOC) analyzers have been designed for straightforward analysis of these waters, with special features to avoid many of the problems found with salty samples. The presence of the chloride ion (Cl) in waters being analyzed for carbon presents problems when the method uses low temp...

A wet-oxidation method is presented for determining simultaneously particulate organic carbon (POC), particulate organic nitrogen (PON) and particulate organic phosphorus (POP) collected on filters. Conversion of POC, PON and POP to inorganic products, carbon dioxide, nitrate+nitrite and soluble reactive phosphate respectively, is performed by a persulfate wet-oxidation in slight alkaline condi...

Increasing quantities of pharmaceutical pollutants have been found in aquatic ecosystems. The treatment has a major task that people committed to recent years. removal can be achieved by adsorption and advanced oxidation processes (AOPs). Compared with other carbon materials, biochar strong capacity persulfate activation ability, more importantly, is cheap easy obtain; thus, it higher economic ...