Two novel manganese (III) and iron complexes of an N,N-bis(1-naphthalidimine)-o phenylene diamine ligand have been successfully synthesized characterized by various analytical techniques including single crystal X-ray structure analysis. The crystallizes in the monoclinic system with space group P21/c. detailed analyses Hirschfeld surface fingerprint plots provide insight into nature non-covale...

We use molecular dynamics simulations at the atomistic level to build a model of aromatic polyamide polymer used in reverse osmosis membranes, from mixture m-phenylene diamine (MPD) and trimesoyl chloride monomers (TMC). Our purpose is different MPD TMC ratios reproduce compositional depth-dependence observed experimentally during interfacial polymerization. range 1:4 5:1 have been employed. Re...

Two different kinds of copper nanoparticles (CuNPs) (brown colour and greenish colour) were synthesised by using simple solution route applied exhaust method to achieve multidimensional functionalization on one the most popular cellulose materials e.g., cotton fabric. The CuNPs imparted colours said textile due conditions synthesis localized surface plasmon resonance. Physico-chemical character...

Thin film composite (TFC) membranes have been experiencing significant modifications recently aiming to improve their structure, properties and separation efficiency. One of the promising tailor more efficient is changing materials used. m -phenylene diamine (MPD), piperazine (PIP), trimesoyl chloride (TMC) are most common monomers used fabricate TFC membranes. Recent studies introduced several...

An electrochemical sensor based on a molecularly imprinted polymer membrane (MIP) was developed. The prepared by electropolymerization of o-phenylenediamine (O-PD) the surface glassy carbon electrode (GCE), modified AuNPs@covalent organic framework (COF) microspheres with ascorbic acid (AA) as template molecule. First, ultrasmall polyvinylpyrrolidone (PVP)-coated AuNPs were chemical reduction m...

Abstract The toxicity of propachlor (PROP) with its chloroacetanilide members is reported. Rapid and sensitive detection PROP critical for ecotoxicity evaluation the removal process. A novel voltammetric sensor developed based on imprinted poly (o-phenylene diamine-co-pyrrole) (o-PD-co-Py) electrochemically reduced graphene oxide (ERGO) to detect at a trace level. use ERGO provides high density...