the preparation of polymer membrane selective to iron(ii) ion and its application to ion-selectiveelectrode is reported here. pvc membrane contains iron–selective n-phenylaza-15-crown-5 asionophore. the membrane electrode is highly selective to iron(ii) ion and exhibit good linearresponse over a wide concentration range of 1.0 × 10-2 to 1.0 × 10-6 m with nernstian slope of29.2 ± 0.6 mv per deca...

Abstract The low-temperature electrolysis of CO 2 in membrane-based flow reactors is a promising technology for converting captured into valuable chemicals and fuels. In recent years, substantial improvements reactor design have significantly improved the economic viability this technology; thus, field has experienced rapid increase research interest. Among factors related to design, ion exchan...

Proton exchange membrane water electrolysis (PEMWE) is a green hydrogen production technology with great development prospects. As an important part of PEMWE, bipolar plates (BPs) play role and put forward special requirements due to the harsh environments on both anode cathode. Recently, metal-based BPs, particularly stainless steel titanium BPs have attracted much attention from researchers a...

The separator is a critical component for the performance of alkaline water electrolysis as it ensures ionic contact between electrodes and prevents product gases from mixing. While conductivity affects cell voltage, permeability dissolved influences gas impurity. Currently, diaphragms are used separators, pore system which filled with electrolyte solution to enable exchange ions. breakthrough ...

─The Nafion/zeolite composite membranes were synthesized for polymer electrolyte fuel cells (PEMFCs) by adding zeolite in the matrix of Nafion polymer. Two kinds of zeolites, Analcime and Faujasite, were used. The physicochemical properties of the composite membranes such as water uptake, ion-exchange capacity, hydrogen permeability, and proton conductivity were determined. The fabricated compo...

in present research work, homogeneous anion exchange membranes based on polysulfone (qapsfs) were prepared via chloromethylation, amination and alkalization. in amination step, trimethylamine and n,n,n',n'-tetramethyl-1,6-hexanediamine were used as amination and crosslinking agents, respectively. the chloromethylated polysulfone was characterized by 1hnmr spectroscopy and chloromethylation degr...

in the current research, polyvinylchloride based mixed matrix heterogeneous anion exchange membranes were prepared by a solution casting technique. titanium dioxide nanoparticles were also utilized as inorganic filler additive in the membrane fabrication. the effect of tio2 nanoparticles concentration in the casting solution on the membrane physico-chemical properties was studied. membrane wate...

Vinylbenzyl chloride was grafted onto PVDF and FEP polymer films using the radiation-grafting methodology. Subsequent reaction with trimethylamine and ion-exchange with potassium hydroxide yields alkaline anion-exchange membranes that are capable of conducting hydroxide ions; such membranes may be suitable for use in low temperature direct methanol fuel cells for portable devices. The PVDF base...

Blend reverse osmosis membranes were fabricated using polyvinyl chloride (PVC) with cellulose acetate (CA) as polymer blends. Tetrahydrofuran (THF) and N-Methyl-2-pyrrolidone (NMP) were used as solvents. The membrane polymer solution was cast on a coated woven fabric support material. The prepared membranes have been characterized by SEM and mechanical properties. SEM r...

Nowadays, proton exchange membrane fuel cells (PEMFCs) are the most promising green energy conversion devices for portable and stationary applications. Traditionally, these devices were based onperfluoro-sulfonic acid electrolytes membranes, given the commercial name Nafion. Nafion is the mostused electrolyte membrane till now; because of its high electrochemical properties su...