A rapid progress in the theoretical developments based on modulations of absorption cross section due to single and multiple scattering of an electron emitted from an inner shell by X-rays impinging on the target atom to understand the EXAFS and XANES in recent years and harnessing of the highly powerful synchrotron radiation source for the X-rays have bestowed immense capability on X-ray absor...

Spinel zinc manganese oxide (ZnMn2O4) nanorods were successfully prepared using the previously synthesized α-MnO2 nanorods by a hydrothermal method as template. The nanorods were characterized by X-ray diffraction, scanning electron microscopy, transmission electron microscopy, UV-Vis absorption, X-ray photoelectron spectroscopy, surface photovoltage spectroscopy, and Fourier transform infrared...

x-ray absorption fine structure (xafs) spectroscopy was used to identify directly the metal speciation and local bonding environment of fe in sediments originated from dobczyce reservoir (poland); special attention was paid to analysis of samples collected from points situated at different distances from the land. the combination of traditional approach to data analysis as well as usage of mult...

A laser driven electron x-ray source (LEXS) emitting tungsten Lα lines has been built based on a high repetition rate, terawatt laser system. The Lα characteristic lines overlap with the absorption edge of Ni near 8333 eV. Using this x-ray source, the x-ray absorption spectra near the absorption edge of different Ni compounds have been measured. We term this new method “ultrafast selected energ...

x-ray absorption fine structure (xafs) spectroscopy was used to identify directly the metal speciation and local bonding environment of fe in sediments originated from dobczyce reservoir (poland); special attention was paid to analysis of samples collected from points situated at different distances from the land. the combination of traditional approach to data analysis as well as usage of mult...

The magnetic and electronic properties of single-molecule magnets are studied by X-ray absorption spectroscopy and X-ray magnetic circular dichroism. We study the magnetic coupling of ultrathin Co and Ni films that are epitaxially grown onto a Cu(100) substrate, to an in situ deposited submonolayer of TbPc2 molecules. Because of the element specificity of the X-ray absorption spectroscopy we ar...

Calcium fluoride nanoparticles with special amount of cerium ion (%1) were synthesized by coprecipitation. Fourier transforms infrared spectroscopy (FTIR), X-ray diffraction (XRD), absorption and photoluminescence (PL) from CaF2Ce nanoparticles has been investigated. FTIR spectra reveal that there are some amounts of OH, NO3 and other organic functional groups on the parti...

We present a robust data analysis method of time-resolved x-ray absorption spectroscopy experiments suitable for chemical speciation and structure determination of reaction intermediates. Chemical speciation is done by principal component analysis (PCA) of the time-resolved x-ray absorption near-edge structure data. Structural analysis of intermediate phases is done by theoretical modeling of t...

We describe a laser-driven x-ray plasma source designed for ultrafast x-ray absorption spectroscopy. The source is comprised of a 1 kHz, 20 W, femtosecond pulsed infrared laser and a water target. We present the x-ray spectra as a function of laser energy and pulse duration. Additionally, we investigate the plasma temperature and photon flux as we vary the laser energy. We obtain a 75 μm FWHM x...

Strong characteristic Kα X-ray lines are accompanied by weak lines due to the radiative Auger effect (RAE) [1, 2]. The characteristic Kα fluorescent X-rays (K-L2,3 lines) are emitted by the 2p→1s electric dipole transition after one of the 1s electron photoionization, Though the probability is less than 0.01, one of the 2p electrons is excited into an unoccupied discrete or continuum level simu...