A dicompartmental Schiff base ligand was synthesized and used for the assembly of a lanthanide grid-like complex. Dinuclear Dy2 tetranuclear Dy4 complexes were isolated from reaction with different dysprosium salt. Single crystal X-ray diffractions show that two DyIII ions in are adopted N3O coordination pockets further coordinated by water molecules, whereas, Dy4, four clamped ligands through ...