نتایج جستجو برای: recyclable catalyst
تعداد نتایج: 46044 فیلتر نتایج به سال:
Monoclinic CuO crystallite in grams has been obtained from resin bound Cu(II)-1,10-phenanthroline complex, R(-)[Cu(1,10-phen)(2)](2+) that becomes a recyclable catalyst for oxidative phenol coupling (OPC) reaction. Thus an exclusively intuitive blue fluorescing perylene derivative is derived from colorless 2,7-dihydroxynaphthalene (2,7-DHN) in high yield.
This review presents a summary of reactions performed using microwave irradiation. This green processes have resulted through use of less or no catalyst, readily recyclable solvents and yield that are often higher than conventional method. It also focus on the principle of microwave activation, various types of Microwave Reactor and its characteristics.
A highly efficient and recyclable Ir catalyst bearing a 4,7-dihydroxy-1,10-phenanthroline ligand was developed for the evolution of high-pressure H2 gas (>100 MPa), and a large amount of atmospheric pressure H2 gas (>120 L), over a long term (3.5 months). The reaction proceeds through the dehydrogenation of highly concentrated aqueous formic acid (FA, 40 vol %, 10 mol L-1 ) at 80 °C using 1 μmo...
CuI nanoparticles as an expedient and recyclable catalyst for the synthesis of N-cyclohexyl-3-aryl-quinoxaline-2-amines in ethanol via a multi-component reaction are established. The products were separated from the catalyst simply by filtration. The catalyst could be recycled and reused for several times without noticeably decreasing the catalytic activity.
sulfuric acid ([3-(3-silicapropyl)sulfanyl]propyl]ester (saspspe) is employed as a recyclable catalyst for the silylation of hydroxyl groups. a good range of primary, secondary alcohols and phenolic hydroxyl groups were effectively converted into their corresponding trimethylsilyl ethers with hexamethyldisilazane in the presence of catalytic amounts of saspspe at room temperature with short rea...
an efficient synthesis route to 1,4-dihydropyrimidine derivatives from reaction of divergent aldehydes with ethylacetoacetate and urea under solvent-free conditions by zno nanoparticles as a relative in expansive, eco-friendly, easy available, non-volatile, non-explosion, thermally robust, recyclable and easy to handle catalyst at 90°c with excellent yields is described. unenhanced reaction tim...
CuO-CeO2 nanocomposite is reported as a green and highly efficient recyclable catalyst for the multicomponent synthesis of 3,4-dihydropyrimidin-2(1H)-ones/thiones under solvent-free conditions. The catalyst was synthesized by co-precipitation method and characterized by XRD, BET specific surface area, FESEM and EDS analysis.
A facile and robust approach is provided for the synthesis of highly dispersed copper nanoparticles immobilized onto graphene nanosheets, useful as a recyclable and reusable heterogeneous catalyst with excellent catalytic activity to achieve Cu(I)-catalyzed [3+2] cycloaddition 'click' chemistry.
We have developed an effective method that converts a variety of mono- and disaccharides into formic acid predominantly. Our recyclable NHC-amidate palladium(II) catalyst facilitated oxidative degradation of carbohydrates without using excess oxidant. Stoichiometric amounts of hydrogen peroxide and sodium hydroxide were employed at ambient temperatures.
The synthesis of a monosilylated Grubbs-Hoveyda ruthenium alkylidene complex is described, as well as the preparation and characterization of the corresponding material by sol-gel cogelification with tetraethoxysilane (TEOS) and the assay of this recyclable supported catalyst in ring-closing diene and enyne metathesis reactions under thermal and microwave conditions.
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