DFT calculations show that a combination of an electric field and electronic excitation is promising mechanism to force molecular switch based on amino-imino tautomerisation into one its two states. By calculating the effect in direction moving hydrogen shape barrier ground low-lying excited states previously proposed switches consisting 5- 7-membered rings with adjacent amino imino groups, we ...

The structure and dynamic behaviour of monomeric lead(ii) dithiolate Pb(SCH(2)CH(2)NMe(2))(2) are studied by multi-nuclear NMR, IR and Raman spectroscopy in solution, as well as variable-temperature Raman spectroscopy and X-ray diffraction analysis in the solid-state, revealing an unusual dynamic "flip-flop" process in solution and reversible conformational isomerism of the chelated five-member...

It has equilibrium (and in fact reversible) measure μ the product Bernoulli measure of density p on {0, 1}Z. It can also be constructed by attaching a Poisson process clock to every site in Z. Every time a clock rings, the site is refreshed to a Bernoulli variable of parameter p, but only if its right neighbour is empty. This constraint creates the ”bubbles” one can see on the picture. A natura...

A new dual-boron-cored luminogen ligated with a nitrogen-containing multidentate ligand and four bulky phenyl rings was readily synthesized. The unique molecular structure endows this BN-containing luminogen with rich photophysical properties in either solution or in the solid state, including a large Stokes shift, aggregation induced emission activity and reversible piezochromism. Furthermore,...

Abstract During an extensive test programme at the Bundesanstalt für Materialforschung und prüfung, material property changes of EPDM O-rings were investigated different ageing times and two temperatures $$125\,^{\circ }\,\hbox {C}$$ 125 ∘ C</mm...

Today, the use of CMOS technology for the manufacture of electronic ICs has faced many limitations. Many alternatives to CMOS technology are offered and made every day. Quantum-dot cellular automata (QCA) is one of the most widely used. QCA gates and circuits have many advantages including small size, low power consumption and high speed. On the other hand, using special digital gates called re...

for any reduced commutative $f$-ring with identity and bounded inversion, we show that a condition which is obviously necessary for the socle of the ring to coincide with the socle of its bounded part, is actually also sufficient. the condition is that every minimal ideal of the ring consist entirely of bounded elements. it is not too stringent, and is satisfied, for instance, by rings of conti...

recently testing of quantum-dot cellular automata (qca) circuits has attracted a lot of attention. in this paper, qca is investigated for testable implementations of reversible logic. to amplify testability in reversible qca circuits, a test method regarding to built in self test technique is developed for detecting all simulated defects. a new reversible qca mux 2×1 design is proposed for the ...

for a fixed positive integer , we say a ring with identity is n-generalized right principally quasi-baer, if for any principal right ideal of , the right annihilator of is generated by an idempotent. this class of rings includes the right principally quasi-baer rings and hence all prime rings. a certain n-generalized principally quasi-baer subring of the matrix ring are studied, and connections...

DNA topoisomerase activity detected in cell extracts of the trypanosomatid Crithidia fasciculata interlocks kinetoplast DNA duplex minicircles into huge catenane forms resembling the natural kinetoplast DNA networks found in trypanosomes. Catenation of duplex DNA circles is reversible and equilibrium is affected by ionic strength, and by spermidine. The reaction requires magnesium, is ATP depen...