نتایج جستجو برای: selectivity factor
تعداد نتایج: 887182 فیلتر نتایج به سال:
New chiral catalyst systems were developed for the reaction of carbon dioxide with propylene oxide (PO) at atmospheric pressure to generate enantiomerically enriched propylene carbonate (PC). The best selectivity was achieved with a Co(III)(salen)-trifluoroacetyl complex and bis(triphenylphosphoranylidene)ammonium fluoride (PPN+F-) as catalysts, affording PC in 40% yield and 83% ee (selectivity...
در سال های اخیر، کاربرد مدل های هیدرولوژیکی توزیعی بر پایه فیزیکی افزایش یافته است. با این حال بسیاری از سوالات در خصوص واسنجی و صحت سنجی صحیح مدل های توزیعی و ارزیابی عدم قطعیت پارامترهای تخمینی، هنوز هم ناشناخته است. به خصوص برای مدل های پیچیده، تخمین پارامترها به طور صحیح، کاهش فضای پارامتری و استفاده از الگوریتم های موثر و کارآمد به منظور کاهش عدم قطعیت و تسهیل فرآیند واسنجی امری ضروریست. ه...
در این تحقیق به بررسی پارامترهای بیلان آب حوضه رودخانه آق چای در شمال استان آذربایجان غربی، با مساحت 1440.89 کیلومتر مربع پرداخته شده است. مدل سازی بارش-رواناب با گام زمانی روزانه و با استفاده از مدل نیمه توزیعی swat و بهینه سازی پارامترهای حوضه، بررسی عدم قطعیت مدل و پارامترها با برنامه swat-cup انجام گرفته است. کاربرد الگوریتم sufi-2 در بررسی عدم قطعیت نشان داد مقدار ضریب ناش برای دوره واسنج...
Mental imagery is involved in a wide variety of cognitive abilities, including reasoning, spatial navigation, and memory. Cognitive aging is associated with impairments in these abilities, suggesting that diminished fidelity of mental images in older adults may be related to diverse cognitive deficits. However, an age-related deficit in mental imagery and its role in memory impairment is still ...
Rna15 is a core subunit of cleavage factor IA (CFIA), an essential transcriptional 3'-end processing factor from Saccharomyces cerevisiae. CFIA is required for polyA site selection/cleavage targeting RNA sequences that surround polyadenylation sites in the 3'-UTR of RNA polymerase-II transcripts. RNA recognition by CFIA is mediated by an RNA recognition motif (RRM) contained in the Rna15 subuni...
Metal-organic frameworks offer tremendous potential for efficient separation of molecular mixtures. Different pore sizes and suitable functionalizations of the framework allow for an adjustment of the static selectivity. Here we report membranes which offer dynamic control of the selectivity by remote signals, thus enabling a continuous adjustment of the permeate flux. This is realized by assem...
Beaded molecule imprinted polymer (MIP) was made by suspension polymerization. Particles with the size of 50-70 microns in diameter were collected and evaluated in HPLC mode to separate stereo isomers. Stereo isomers cinchonine and cinchonidine were successfully discriminated with selectivity factor of 2.89 and resolution factor of 0.76. Stereo selectivity of the MIP was found to come from both...
the possibility of selective leaching process was investigated during molybdenite flue dust leaching to recover its rhenium content. the results show that addition of alcohols to water makes the medium less favorable for molybdenum transfer into aqueous phase. on the other hand, addition of small amounts of alcohols (5-15%) makes a noticeable separation of rhenium over molybdenum, but by increa...
A DNA array detection method is reported in which the binding of oligonucleotides functionalized with gold nanoparticles leads to conductivity changes associated with target-probe binding events. The binding events localize gold nanoparticles in an electrode gap; silver deposition facilitated by these nanoparticles bridges the gap and leads to readily measurable conductivity changes. An unusual...
in a novel dual bed reactor fischer-tropsch synthesis was studied by using two diffrent cobalt catalysts. an alkali-promoted cobalt catalyst was used in the first bed of a fixed-bed reactor followed by a rutenuim promoted cobalt catalyst in the second bed. the activity, product selectivity and accelerated deactivation of the system were assessed and compared with a conventional single bed react...
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