Single-Crystal Diamond DetectorsA high-performance single-crystal diamond (SCD) detector (4.5 × 4.5 0.3 mm3) is demonstrated in article number 2100138 by Chun-Zhi Zhou, Yi-Yun Zhang, and co-workers. Enabled a machine learning method based on self-organizing map neural networks as proof of concept, the SCD has its potential for accurate pulse shape discrimination, which can effectively distingui...

Abstract The synthesis and structural characterization of the novel triruthenium nitrosyl cluster [Ru 3 (μ‐NO)(CO) 5 (μ‐H)(μ‐PBu t 2 ) (μ‐dppm)] ( is described. Compound was obtained by reaction 46‐valence electron (μ‐CO)(CO) 4 (μ ‐H)(μ‐H)(μ‐PBu 1 with nitric oxide on other hand in a more efficient way transfer reagent triphenylmethyl thionitrite (TTN). NO outlined dichloromethane whereas TTN r...

Well-defined model catalyst samples, prepared under ultra-high-vacuum (UHV) conditions, hold the potential of bridging the gap between traditional surface science and technical catalysis studies. However, work remains to understand and characterize reaction kinetics of such samples under more realistic pressure conditions, specifically, how reaction kinetics of a well-studied reaction (such as ...

The adsorption and dissociation of carbon dioxide on a Ru(0001) single crystal surface was investigated by reflection-absorption infrared spectroscopy (RAIRS) and temperature-programmed desorption (TPD) spectroscopy for CO2 adsorbed at 85 K. RAIRS spectroscopy shows that the adsorption of CO2 on a Ru(0001) single crystal is partially dissociative, resulting in CO2 and CO. The CO vibrational mod...

A [Co(6)(μ(3)-OH)(4)(datrz)(2)](6+) ribbon-based blue framework with a metamagnetic transition from an antiferromagnetic ordering to a weak spontaneous magnetization state, {[Co(3)(CH(3)OH)(μ(3)-OH)(2)(datrz)(sip)]·2.25H(2)O}(n) (1, Hdatrz = 3,5-diamino-1,2,4-triazole, sip(3-) = 3,5-dicarboxybenzenesulfonate), was solvothermally synthesized. 1 exhibits a reversible single-crystal-to-single-crys...