Chemical and magnetic states of iron doped tin oxide (SnO2) as a diluted magnetic semiconductor (DMS) at room temperature have been investigated using 57Fe Mössbauer spectrometry, XRD and magnetometery. The influence of the doping conditions of SnO2 with iron on the generation of oxygen defects was reviewed and discussed on the basis of ab initio calculations. The magnetic properties depended o...

In this report, we show for the first time that SnO2 nanowire based dye sensitized solar cells exhibit an open circuit voltage of 560mV, which is 200mV higher than that using SnO2 nanoparticle based cells. This is attributed to the more negative flat band potential of nanowires compared to the nanoparticles as determined by open circuit photo voltage measurements made at high light intensities....

A SnO2 nanocrystallite-based photoanode was prepared using tin (iv) chloride and fructose via a one-pot hydrothermal method, and its structural and morphological properties were studied. Structural observations revealed tetragonal crystals of SnO2, and morphological studies confirmed the presence of spherical nanoparticulates. Furthermore, encapsulating the surface of the SnO2 photoanode (+N719...

Wire-like SnO2 is fabricated by the wet chemical method. X-ray diffraction measurements show that the obtained samples have rutile-type structure. Electron transmission microscopy experiments illustrate that the wire-like SnO2 ranged from 10 to 50 nm in width and several microns (μm) in length. The high-resolution TEM indicates that SnO2 wires are single crystals. The possible growth mechanism ...

Olive-shaped SnO2 nanocrystals were synthesized successfully via a facile hydrothermal route, using tin dichloride hydrate, oxalic acid dihydrate and polyvinylpyrrolidone as reaction precursors, and showed great potential in the large-scale preparation of SnO2 nanocrystals. The prepared SnO2 nanocrystals were characterized using XRD, XPS, SEM, TEM and HRTEM, and showed well-defined olive-shaped...

SnO2 nanowire arrays were synthesized by fast heating a mixture of SnO2 and the carbon nanotubes waste soot by high-frequency induction heating. The resultant SnO2 nanowires possess diameters from 50 to 100 nm and lengths up to tens of mircrometers. The field-effect transistors based on single SnO2 nanowire exhibit that as-synthesized nanowires have better transistor performance in terms of tra...

Self-assembled, aggregated, chain-like SnO2 nano-assemblies were synthesized at room temperature by a simple wet chemical route within an hour in the presence of DNA as a scaffold. The average size of the SnO2 particles and the chain diameter were controlled by tuning the DNA to Sn(ii) molar ratio and altering the other reaction parameters. A formation and growth mechanism of the SnO2 NPs on DN...

The morphology of SnO2 nanospheres was transformed into ultrathin nanosheets assembled architectures after Zn doping by one-step hydrothermal route. The as-prepared samples were characterized in detail by various analytical techniques including scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), and nitrogen adsorption-desorption technique. The Z...

Direct bandgap semiconductors, such as In2O3, Cu2O, and SnO2, have enormous applications in photochemistry, photovoltaics, and optoelectronics. Due to the same parity of conduction and valence bands, the dipole transition is silent in these direct bandgap semiconductors. The low band-to-band transition efficiency prevents them from high intensity light emission or absorption. Here, we report th...

Tin oxide (SnO2) is an important oxide for efficient dielectrics, catalysis, sensor devices, electrodes and transparent conducting coating oxide technologies. SnO2 thin film is widely used in glass applications due to its low infra-red heat emissivity. In this work, the SnO2 electronic band-edge structure and optical properties are studied employing a first-principle and fully relativistic full...