the complexation reactions of some transition metal ions and 2-aminopyridine (2-ampy) were studied potentiometrically in aqueous solution at µ=0.1 m and 25 °c. the overall stability constants log β’s of all species are obtained by computer refinement of ph-volume data with using the best computer program. several models were tested and the best one accepted according to the least sum of squared...

The stability constants of Fe(III) and Cr(III) with methyl cysteine and nitrilotriacetate (NTA) were determined by paper electrophoretic technique. Beside binary ternary complexes have also been studied, in which nitrilotriacetate and methyl cysteine acts as primary and secondary ligand, respectively. The stability constants of mixed ligand complexes metal (M)-nitrilotriacetate-methyl cysteine ...

The stability constants of Mn(II), Fe(II) and Zn (II) with p-Chloro Malonamic acid (PCMA), pAmino Malonamic Acid (PAMA), p-Nitro Malonamic Acid (PNMA) different percentage of dioxane water has been determined pontentiometrically by Calvin-Bjerrum titrations. The titrations were carried out at constant ionic strength (0.1 M) and constant temperature i.e. 27±0.1°C. The data obtained can be used t...

In this paper, a link between the Hyers–Ulam stability and the Moore–Penrose inverse is established, that is, a closed operator has the Hyers–Ulam stability if and only if it has a bounded Moore–Penrose inverse. Meanwhile, the stability constant can be determined in terms of the Moore– Penrose inverse. Based on this result, some conditions for the perturbed operators having the Hyers– Ulam stab...

Conditional stability constants have been determined for U(IV) and U(VI) Boom Clay humic acid (BCHA) and Aldrich humic acid (AHA) complexes, under anaerobic and carbonate free conditions. The constants are needed for nuclear waste repository performance assessment purposes. The U(IV) constants were obtained by developing an approach based on the solubility product of amorphous U(OH)4. The U(VI)...

Chemical speciation of Pb(II), Cd(II), Hg(II), Co(II), Ni(II), Cu(II) and Zn(II) complexes of L-glutamic acid was studied at 303 K in 0–60 vol. % 1,2-propanediol–water mixtures, whereby the ionic strength was maintained at 0.16 mol dm-3. The active forms of the ligand are  3 LH , LH2 and LH–. The predominant detected species were ML, ML2, MLH, ML2H and ML2H2. The trend of the variation in the ...