ABSTRACT Advances in Nuclear Magnetic Resonance (NMR) spectroscopy is a cornerstone structure elucidation of polycyclic 'cage' scaffolds. Due to the compactness these compounds, much overlap, as well unique through-space and bond NMR interactions are frequently observed. This review serves guide for future derivatives by providing some typical relevant aspects characteristic trends, substituent...

The ideal of computer assisted structure elucidation (CASE) is to generate, exhaustively and without redundancy, all possible structures that are consistent with a particular set of spectroscopic data. The aim is to achieve this goal with the minimum amount of human intervention. In natural product drug discovery the major bottleneck has always been structure elucidation, and it is with this in...

The elucidation of new structure–property relationships in π-conjugated molecules bearing quinoidal moieties is relevance organic electronics applications and as models doped conducting polymers.

Natural products continue to be reported at an astonishing rate from a wide range of multidisciplinary research activities in the pursuit understanding chemistry biodiversity. However, elucidation chemical structure modern era is heavily reliant on analysis and interpretation multiple spectroscopic outputs, most cases this activity by no means trivial. Structural errors described given inherent...