So-called "sulfur-turf" microbial mats in sulfide containing hot springs (55-70°C, pH 7.3-8.3) in Japan were dominated by a large sausage-shaped bacterium (LSSB) that is closely related to the genus Sulfurihydrogenibium. Several previous reports proposed that the LSSB would be involved in sulfide oxidation in hot spring. However, the LSSB has not been isolated yet, thus there has been no clear ...

The formation and fate of sulfide in a force main and a downstream-located gravity sewer were investigated in an extensive field study. Sulfide formation in the force main was significant. However, during 14 minutes of transport in the gravity sewer, the sulfide concentration decreased 30%, on average. An application of a conceptual sewer process model for simulating the formation and fate of s...

In many Dutch freshwater wetlands, concentrations of sulfate in the surface water and groundwater have increased. It is especially in peaty areas that this can lead to problems, including the reduction of sulfate to toxic sulfide. Our aquarium experiments showed that even low sulfide concentrations of 50 micromol/L are toxic to the freshwater macrophyte Nitella flexilis and the freshwater oligo...

A procedure for measuring in situ sulfide concentrations by coupling diffusive gradients in thin films (DGT) to solid-state ion-selective electrodes (ISE) is described and evaluated. Laboratory tests were performed to evaluate the coupling of these techniques, and these results were compared to the previously used methods of computer imaging densitometry (CID) and methylene blue. An average elu...

Transient-state experiments with the obligately autotrophic Thiobacillus sp. strain W5 revealed that sulfide oxidation proceeds in two physiological phases, (i) the sulfate-producing phase and (ii) the sulfur- and sulfate-producing phase, after which sulfide toxicity occurs. Specific sulfur-producing characteristics were independent of the growth rate. Sulfur formation was shown to occur when t...

The chlorinated fumigants chloropicrin (trichloronitromethane) and 1,3-dichloropropene (1,3-D) are extensively used in agricultural production for the control of soilborne pests. The reaction of these two fumigants with hydrogen sulfide species (H2S and HS-) was examined in well-defined anoxic aqueous solutions. Chloropicrin underwent an extremely rapid redox reaction in the hydrogen sulfide so...

Higher solubility at alkaline conditions is very significant for an efficient treatment process of gaseous H2S(g) by reducing the gas–liquid ransfer limitations. Nevertheless, the alkaline biodegradation process of H2S can be limited when sulfide concentrations are inhibitory. At alkaline onditions (pH > 9), the abiotic chemical sulfide oxidation can attain relatively high rates. A series of ab...

Although essential in critical care medicine, mechanical ventilation often results in ventilator-induced lung injury. Low concentrations of hydrogen sulfide have been proven to have anti-inflammatory and anti-oxidative effects in the lung. The aim of this study was to analyze the kinetic effects of pre- and posttreatment with hydrogen sulfide in order to prevent lung injury as well as inflammat...

Sulfide (H2S/HS(-)) has been demonstrated to exert an astounding breadth of biological effects, some of which resemble those of nitric oxide (NO). While the chemistry, biochemistry and potential pathophysiology of the cross-talk between sulfide and NO have received considerable attention lately, a comparable assessment of the potential biological implications of an interaction between nitrite a...

The conditional stability constants of metal–sulfide complexes were determined in pH 8 seawater at various salinities, by Ž . flow-analysis with detection by cathodic stripping voltammetry FA-CSV . Two methods were used. The first method was titration of the sulfide by metal with detection of the free sulfide by FA-CSV. The titrant metals were Ag, Cd, Co, 2q 2q 2q 2q 3q 3q Ž . Fe , Mn , Pb , Zn...