The synthesis of modified diketone ligands and the preparation of soluble Er3þ and Eu3þ tris-(b-diketone)phenantroline complexes are described. The complexes, embedded in thin films of different conjugated and non-conjugated polymeric host matrices were studied by luminescence spectroscopy and used as active layers in organic light emitting single layer diodes to observe their characteristic em...

Aim. To summarize and analyze literature data on the polymethine dyes containing 2,2-difluoro-1,3,2-dioxaborine ring.Results discussion. Boron difluoride complex of β-diketone (2,2-difluoro-1,3,2-dioxaborine, F2DB) is a unique structural motif endowing organic compounds with prominent physicochemical properties, such as strong fluorescence high mo-lar attenuation coefficients. Incorporation F2D...

4-Fluoropyrazole systems may be prepared by a single, sequential telescoped two-step continuous gas/liquid-liquid/liquid flow process from diketone, fluorine gas and hydrazine starting materials.

Hybrid organic–inorganic perovskite solar cells (PSCs) are promising new generations of cells, which is low in cost with high power conversion efficiency (PCE). However, PSCs suffer from structural defects generated the under coordinated ions at surface, limits their photovoltaic performances. Herein we report, two β-diketone Lewis base additives 2,4-pentanedione and 3-methyl-2,4-nonanedione wi...

Abstract δ‐Valerolactone derivatives are formed by the cerium‐catalyzed, aerobic coupling of β‐oxoesters with enol acetates and dioxygen. The products possess a 1,4‐diketone moiety, thus, conversion can be regarded as an Umpolung since oxidized to electrophilic α‐radicals. transformation has similarities Baeyer‐Villiger oxidation (BVO) where higher substituted residue migrates. An endoperoxidic...

Angelica gigas NAKAI is used to treat dysmenorrhea, amenorrhea, menopause, abdominal pain, injuries, migraine, and arthritis. The present study provided a physicochemical and toxicological characterization of compounds in A. gigas NAKAI (decursin, decursinol angelate, diketone decursin, ether decursin, epoxide decursin and oxim decursin). Diketone decursin (173.16 μg/mL) and epoxide decursin (1...

Seven new tris(β-diketonear-nate)ytterbium(III) complexes with the general formula [Yb(β-diketonate)3(5NO2phen)] (where the β-diketone is either 4,4,4-trifluoro-1-(2-naphthyl)-1,3-butanedione, 4,4,4-trifluoro-1-(2-furyl)-1,3-butanedione, 1,1,1-trifluoro-2,4-pentanedione, 1,1,1-trifluoro-5,5-dimethyl-2,4-hexanedione, 1,1,1,5,5,6,6,7,7,7-decafluoro-2,4-heptanedione, 2,4-hexanedione or 2,6-dimethy...

The formation of 1,3-diketones was observed in the reactions of bulky acyl chlorides with methyllithium. The reaction products depend on the steric hindrance around the carbonyl group of the acyl chloride and the electronic effect of the group(s) linked to the carbonyl. When the steric hindrance around the carbonyl group of the acyl chloride is big enough, the 1,3-diketone is the only product. ...