In the centrosymmetric dinuclear title compound, [Pd2(C4H7)2(C16H14N2S2)], the metal atom is η(3)-coordinated by three C atoms of a crotyl ligand [Pd-C = 2.147 (4), 2.079 (5) and 2.098 (5) Å], the longest distance influenced by the steric inter-action with the benzyl substituents of the di-benzyl-dithio-oximidate (DTO) ligand. The Pd-N and Pd-S bonds to this ligand are 2.080 (3) and 2.3148 (9) ...

Unsymmetrically substituted allenes (1,2-dienes) are inherently chiral and can be prepared in optically pure form. Nonetheless, to date the allene framework has not been incorporated into ligands for asymmetric catalysis. Since allenes project functionality differently than either tetrahedral carbon or chiral biaryls, they may create complementary chiral environments. This study demonstrates th...

Extraction of impacted third molars is a well-established and documented procedure. Guided tissue regeneration can be used to aid in wound healing and increase osseous tissue formation. To assess the regenerative treatment outcome, several variables are routinely used; these include primarily histology and direct measurement of bone. Other proxy measurements, such as radiographic analysis, clin...

Introduction: We aimed to investigate the effect of right bundle branch block (RBBB) on perfusion and functional parameters in dipyridamole stress/rest Tc99m-MIBI gated myocardial perfusion SPECT (GSPECT) which may be helpful in interpretation of myocardial perfusion imaging. Methods: We studied 73 patients with low pre-test likelihood of coronary artery disease in two groups:  38 patients wit...

Introduction: Tc99m-DMSA renal scan findings of this project was to study aimed to determine the frequency of congenital anomalies of the kidney. Obtain the spectrum of anomalies, can be used for future intervention studies. Using the experience gained from this study and future studies may be conducted and mitigation measures to achieve a specific distribution. Mater...