Consecutive hydroamination/asymmetric transfer hydrogenation under relay catalysis of an achiral gold complex/chiral Brønsted acid binary system has been described for the direct transformation of 2-(2-propynyl)aniline derivatives into tetrahydroquinolines with high enantiomeric purity.

The compostion of the oils from flower and leaf of Achillea mellifolium L. subsp. mellifolium were collected during the flowering priod from Lar area to Damavand montain, altitude 3400 m in July 2003. The essential oils obtained by different methods of distillation (steam distillation and hydro-distillation), the percentage of oils for flower and leaf by steam distillation were 0.2 and 0.05% an...

The compostion of the oils from flower and leaf of Achillea mellifolium L. subsp. mellifolium were collected during the flowering priod from Lar area to Damavand montain, altitude 3400 m in July 2003. The essential oils obtained by different methods of distillation (steam distillation and hydro-distillation), the percentage of oils for flower and leaf by steam distillation were 0.2 and 0.05% an...

We have characterized a novel microorganism, strain HY99, which is capable of aerobic and anaerobic degradation of aniline. Strain HY99 was found to aerobically metabolize aniline via catechol and 2-hydroxymuconic semialdehyde intermediates, and to transform aniline via p-aminobenzoate in anaerobic environments. Physiological and biochemical tests revealed that strain HY99 was most similar to D...

Aniline and o-, m-, and /Moluidine, which are representative of aro matic amines in cigarette smoke, were identified and quantified in human urine. Smokers excreted 3.1 ±2.6 «¿g/24 h of aniline and 6.3 ±3.7 ¿ig/ 24 h of o-toluidine (n = 16). Nonsmokers excreted 2.8 ±2.5 Mg/24 h of aniline and 4.1 ±3.2 un; 24 h of o-toluidine (n = 12). Metaand /»toluidine were detected in the urine of 2 ...

A rapid glycomic profiling method is described wherein N-glycans from plasma samples individually labelled with aniline, 2-aminobenzamide and 2-aminoacridone are mixed, co-injected and separated in the same HILIC-fluorescence run. Transfer of the multiplexed method to UPLC-fluorescence permits an increase in sample throughput from 24 to 864 plasma samples per day.

Using enantioselective M D G C the enantiom eric d istribution o f alkan-(alken-)2-yl-acetates from bananas is achieved. A fter simple acetylation their corresponding alcohols 2-pentanol, 2-hexanol, 2-heptanol and (Z)-4-hepten-2-ol respectively are also exactly stereodifferentiated by the same method. All com pounds investigated esters as well as alcohols exhibit a rem arkable excess o f the (5...