•Highly reducing photocatalytic system•Inexpensive organocatalyst•Borylation of strong C–F, C–O, C–N, and C–S bonds•Various leaving groups >50 examples Cross-coupling reactions are essential tools in the modern synthesis drugs, natural products, materials. The recent developments radical generation have improved expanded classic metal-catalyzed cross-coupling even further. However, sp2 require ...

There is an increasing interest in identifying potent cancer preventive and therapeutic agents against breast cancer. Silymarin, a flavonoid antioxidant isolated from milk thistle, exerts exceptionably high to complete anticarcinogenic effects in tumorigenesis models of epithe!ial origin. In this study, we investigated the anticarcinogenic effect of silymarin and associated molecular mechanisms...

There is an increasing interest in identifying potent cancer preventive and therapeutic agents against breast cancer. Silymarin, a flavonoid antioxidant isolated from milk thistle, exerts exceptionably high to complete anticarcinogenic effects in tumorigenesis models of epithe!ial origin. In this study, we investigated the anticarcinogenic effect of silymarin and associated molecular mechanisms...