In the title salt, C(4)H(8)N(5) (+)·NO(3) (-), a ring N atom of 2,6-diamino-4-methyl-triazine is protonated. Each anion is connected to three neighbouring cations by multiple N-H⋯O hydrogen bonds which, together with N-H⋯N contacts, generate a layer structure.

The present communication reports the chemistry of three linear triborane(5) compounds possessing bulky diamino substituents on the terminal boron atoms. Fluorotriborane 2 was synthesized by a reaction of boryllithium and BF(3)·OEt(2). Halogen exchange reaction of 2 took place by a treatment with ClSiMe(3) to give the corresponding chlorotriborane(5) 3. Addition of silver tetraarylborate to 3 i...

In the title compound, C(5)H(8)N(3) (+)·C(7)H(5)O(2) (-), the pyridine N atom is protonated. The carboxyl-ate group of the benzoate anion is twisted away from the attached ring by 10.91 (9)°. In the crystal structure, N-H⋯O hydrogen bonds between 2,3-diamino-pyridinium cations and benzoate anions, and π-π inter-actions between the pyridinium rings [centroid-centroid distance = 3.6467 (9) Å] for...

Recently there has been increased interest in high nitrogen content “green” energetic materials which are designed to produce relatively non-toxic decomposition products as part of a push to decrease the environmental impact of energetic materials through all phases of their existence. With the use of a T-Jump/Time-of-Flight Mass Spectrometer (T-Jump/TOFMS) capable of high heating rates (up to ...