hen the first trivalent chromium electroplating process was commercially introduced in the mid-l970s, information on the corrosion properties of the deposits and other physical properties was unknown. To obtain a comprehensive understanding about the corrosion properties of trivalent chromium electrodeposits over a variety of nickel deposits, chromium deposits from trivalent chromium electrolyt...

The purpose of this study was to compare the known behavior of hydrogen embrittled high-strength steel to the characteristics of environmentallyinduced stress corrosion failure where hydrogen is continuously generated at the specimen surface. The incubation time for the initiation of slow crack growth was accelerated by prestressing for a fixed time below the lower critical limit. These results...

Steel corrosion is a major cause of degradation in reinforced concrete structures, and there is a need to develop cost-effective methods to detect the initiation of corrosion in such structures. This paper presents a low cost, easy to use fiber optic corrosion sensor for practical application. Thin iron film is deposited on the end surface of a cleaved optical fiber by sputtering. When light is...

−The 2-chlorophenol (2-CP) was oxidized in a continuous anti-corrosive supercritical water system. The variation of decomposition efficiency by the corrosion of zirconium 702 was also studied at the variation of feed concentration and reaction time. According to AES depth profile, the oxygen penetration depth to zirconium was not proportional to the exposure time. It might stem from the formati...

Pitting corrosion is localized accelerated dissolution of metal that occurs as a result of a breakdown of the otherwise protective passive film on the metal surface. This paper provides an overview of the critical factors influencing the pitting corrosion of metals. The phenomenology of pitting corrosion is discussed, including the effects of alloy composition, environment, potential, and tempe...

The high temperature corrosion behavior of sputtered nanocrystalline K38 coating with and without yttrium addition under mixed molten salt film in air was investigated. Accelerated corrosion occurred on the coating without yttrium (Y) addition locally after 60 h exposure at 900 °C, which resulted in negative weight gain in kinetics. A uniform and protective alumina scale formed on surface of th...

This Laboratory Directed Research & Development (LDRD) project conducted in fiscal years 1996 and 1997 under case 3526.030 was devoted to the development of test structures and associated measurement methodology for assessing the reliability of plastic encapsulated microelectronic devices. The end goal was the conceptual specification of one or more Assembly Test Chips (ATCs) which could be use...