A novel method for indirect determination of MCPD esters levels in lipid samples has been developed. The method is based on combination of extraction and derivatization in the same sample preparation step. It is achieved by the application of diethyl ether as extraction solvent for isolation of analytes released from esterified forms from the water phase and as dilution solvent for solid PBA - ...

A fibrous cellulose powder (CF-1) was investigated as a drying agent for supercritical fluid extraction (SFE) and pressurized liquid extraction (PLE), also known as accelerated solvent extraction. Analysis of fifty-eight diverse pesticides was performed using gas chromatography-ion-trap mass spectrometric detection (GC-ITD). Extraction efficiencies were correlated versus pesticide polarity with...

An ultra-performance liquid chromatography quadrupole time of flight mass spectrometry (UPLC-qTOF-MS/MS) method was developed and validated for the simultaneous determination of glycyrrhizin and glycyrrhetic acid. These analytes were separated on a reverse phase C18 column using a mobile phase of acetonitrile:2% acetic acid in water (75:25, v/v) with a flow rate of 200 μL/min. The qTOF-MS was o...

In this work, we developed a novel graphene-assisted matrix solid-phase dispersion (GA-MSPD) method for extraction of polybrominated diphenyl ethers (PBDEs) and their methoxylated (MeO-) and hydroxylated (OH-) analogs from environmental samples. We found that grinding the solid sample with chemically converted graphene (CCG) powder yielded a tight contact and sufficient dispersion of the sample...

a comparative study of ultrasound-assisted extraction (uae) and hydro-distillation was performed for fast extraction of estragole from tarragon (artemisia dracunculus l.) dried leaves. several influential parameters of the uae procedure in the extraction of estragole (type of solvent, extraction cycles, solvent to material ratio, irradiation time and particle size) were investigated and optimiz...

INTRODUCTION Underground storage tanks containing hydrocarbonbased fuels are found worldwide. Many of these tanks have leaks, allowing gasoline, diesel, oil, or other hydrocarbon materials to contaminate the surrounding soil. In 1992, only 2 million of the 5 million tanks in the U.S. were monitored for leaks. However, underground storage tanks represent only one of many sources of hydrocarbon c...

INTRODUCTION Underground storage tanks containing hydrocarbonbased fuels are found worldwide. Many of these tanks have leaks, allowing gasoline, diesel, oil, or other hydrocarbon materials to contaminate the surrounding soil. In 1992, only 2 million of the 5 million tanks in the U.S. were monitored for leaks. However, underground storage tanks represent only one of many sources of hydrocarbon c...

The work presented in this thesis concerns the development and evaluation of new methods for sampling and analysis of organic pollutants in the indoor and outdoor environment. In Paper I, the development of a new method was reported for the determination of the brominated fl ame retardant tetrabromobisphenol A (TBBPA) in air using sampling with glass fi ber fi lter and polyurethane foam (PUF), ...

oxime extractants 3-tert-butyl-2-hydroxy-5-methyl benzaldehyde oxime (hl1) and 3-tert-butyl-2-hydroxy-5-methoxy benzaldehyde oxime (hl2) were synthesized and characterized by conventional spectroscopic methods. suitable lipophilic nature of the prepared extractants allowed examining the ability of these molecules for extraction-separation of copper from its mixture with normally associated meta...

gallium extraction from jajarm bayer process liquor (jajarm, iran) was investigated using microemulsions. also the behavior of aluminum was studied as an impurity. kelex100 (4-ethyl, 1-methyl, 7-octyl, 8-hydroxyquinoleine), iso-decanol and n-butanol, and kerosene were used as the surfactant, co-surfactant, and oil phase, respectively. ternary phase diagrams were produced using various co-surfac...