A combined experimental and kinetic modeling study is carried out to explore the influences of added acetylene, ethylene, propylene, propyne on reaction schemes benzene pyrolysis. Pyrolysis with without presence C2- or C3- unsaturated hydrocarbons (HCs) conducted in a single pulse shock tube coupled gas chromatography-mass spectrometry technique. minimum 30 species detected each system, their m...

Abstract Tridecacyclene tetraimide, TCTI , an electron‐deficient non‐benzenoid nanocarbon with a C 56 N 4 polycyclic framework was obtained in concise synthesis. has non‐planar structure and forms π‐stacked dimers the solid state. In solution, it undergoes eight single‐electron reductions, yielding range of negatively charged states up to octaanion. Except for latter species, which remarkably l...

The proton resonance spectra of a variety of condensed aromatic compounds including benzene, naphthalene, anthracene, phenanthrene, pyrene, acenaphthylene and triphenylene were obtained in dilute CDCl 3 solution. Comparison of the proton chemical shifts obtained with previous literature data for CCl 4 solution shows small but significant differences. A previous model (CHARGE6) for calculating t...

In this paper we present the convenient syntheses of seven new phenyl hydrazin derivatives 8 (a-h). For this purpose, acenaphtho [1,2-e]-1,2,4-triazine-9(8H)-thione (3) was prepared, starting from acenaphthylene-1, 2-dione (1) and thiosemicabazide in good yield. The reaction of (3) with benzyl chloride resulted to synthesis of 9-(benzylthio)-acenaphtho[1,2-e]-1,2,4-triazines (5) that reacted wi...