High-resolution photoelectron spectroscopy using synchrotron radiation was applied for monitoring in real time the oxidation kinetics on the Ti(0001) surface at 405C with dry O2 gas. The time evolution of O 1s photoelectron intensity showed a linear uptake curve up to ~90 L followed by a sudden saturation up to ~160 L and then a restart of the linear increase, indicating that O2 adsorption obey...

Objective(s):  In our study, graphene oxide-TiO2 nanocomposite (GO/TiO2) was prepared and used for the enrichment of rutin from real samples for the first time.  Materials and Methods:   The synthesized GO/TiO2 was characterized by X-ray diffraction, scanning electron microscopy, and FT-IR spectra.  The enrichment process is fast and highly efficient. The factors including contact time, pH, and...

The human serum albumin (HSA) secondary structure modifications induced by the chrysotile surface have been investigated via computational molecular dynamics (MD) and experimental infrared spectroscopy (FTIR) on synthetic chrysotile nanocrystals coated with different amount of HSA. MD simulations, conducted by placing various albumin subdomains close to the fixed chrysotile surface, show an ini...

A site energy distribution function based on a condensation approximation method is proposed for gas-phase adsorption systems following the Toth isotherm. The proposed model is successfully applied to estimate the site energy distribution of three pitch-based activated carbons (PA, PFeA and PBA) developed in our laboratory and also for other common adsorbent materials for different gas molecule...

The removal of heavy metal ions by the nonliving biomass of aquatic macrophytes was studied. We investigated Cd biosorption by dry Hydrilla verticillata biomass. Data obtained in batch experiments indicate that H. verticillata is an excellent biosorbent for Cd. Cd was rapidly adsorbed and such adsorption reached equilibrium within 20 min. The initial pH of the solution affected Cd sorption effi...

Square-wave cathodic adsorptive stripping voltammetry based on adsorptive accumulation is a very sensitive technique for the trace determination of xanthosine 50-monophosphate (50-XMP) and xanthosine 50-diphosphate (50-XDP). The determination is based on the strong interaction of the adsorption of xanthosine phosphate compounds on a mercury electrode surface, forming Hg(II)-xanthate. The cathod...

A theoretical model is established to describe the response mechanism of surface acoustic wave (SAW) gas sensors based on physical adsorption on the detector surface. Wohljent's method is utilized to describe the relationship of sensor output (frequency shift of SAW oscillator) and the mass loaded on the detector surface. The Brunauer-Emmett-Teller (BET) formula and its improved form are introd...

The purpose of the investigation is to analyze the pros and cons of existing sorption models, as well as experimental methods. In addition, it summarizes existing sorption data in order to understand the phenomenon of VOC sorption on building materials better and to direct future research. We found that existing sorption models can be generally classified into either first order adsorption/deso...

A new Determining Horvath-Kawazoe (DHK) program for the evaluation of pore-size distribution curve based on the HK method (J. Chem. Eng. Jpn. 16 (1983) 470) is described. The standard bisection procedure (Gerald, C.F., 1977. Applied Numerical Analysis, 2nd ed. Addison-Wesley, CA) is used as a kernel in the proposed algorithm. The calculation of the effective pore-size distribution and the compa...

Advanced techniques have greatly promoted the exploitation of shale gas from shale matrix with low permeability. But the gas transport mechanism in shale is still unclear. Due to the multi-scale pore systems in a shale reservoir, viscous flow, slip flow, Knudsen diffusion and adsorption/desorption should be applied to the flowing equation so that it can properly predict gas flow dynamics. Multi...