1. The relative permeability of the native P2X receptor channel to monovalent and divalent inorganic and organic cations was determined from reversal potential measurements of ATP-evoked currents in parasympathetic neurones dissociated from rat submandibular ganglia using the dialysed whole-cell patch clamp technique. 2. The P2X receptor-channel exhibited weak selectivity among the alkali metal...

Macropolycyclic ligands containing appropriate binding sites and cavities of suitable size and shape, may be designed so as to display molecular recognition in the formation of selective inclusion complexes, cryptates, with metal cations, but also with anions and molecules. Macrobicyclic ligands B form highly stable and selective alkali and alkaline-earth cryptates, displaying a pronounced cryp...

Abstract Glycerol can be converted to propylene glycol via metal and base catalyzed hydrogenolysis. The nature of the has a profound influence on outcome reaction. We have tested range alkaline (LiOH, NaOH CsOH) earth (Mg(OH) 2 , Ca(OH) Sr(OH) Ba(OH) ) hydroxides in combination with Pt/C. data reveal that exhibit much higher activity improved selectivity. DFT calculations confirm coordination r...

The structures of isolated alkaline earth metal cationized amino acids are investigated using infrared multiple photon dissociation (IRMPD) spectroscopy and theory. These results indicate that arginine, glutamine, proline, serine, and valine all adopt zwitterionic structures when complexed with divalent barium. The IRMPD spectra for these ions exhibit bands assigned to carboxylate stretching mo...

The interactions of phenazino-crown ether ligands with alkali, alkaline earth and selected toxic species were investigated using density functional theory modelling by employing B3PW91/6-311G ++ (d, p) level of theory. The complex stability was analysed in terms of binding energies, perturbation energies, position of highest molecular orbital and energy gap values. In general, the complexes for...

• New concept accelerating photocatalytic reactions by equilibrium shift is reported. The decomposition of S containing organics was chosen to confirm the concept. accelerated degradation methylene blue and acid yellow42 achieved. removal oxide species (as sulfates) proved as evidence. present can be applied various catalytic reactions. Photocatalytic sulphur in water substantially in-situ form...

the acute toxicity of salts of alkali and alkaline earth metals, such as sodium (na), potassium (k), calcium (ca) and magnesium (mg) were studied on the egg and larval stages of indian major carp labeo rohita (hamilton). the acute toxicity experiments were conducted followed by the range finding bioassay tests. the experiments were conducted in triplicates. the cumulative percentage of dead or ...

INTRODUCTION In 1975, Small and coworkers first introduced the concept of ion chromatography (IC) that allowed the sensitive detection of ions using suppressed conductivity detection. A significant portion of this work was dedicated to cation analysis. The original components described by Small et al. for the separation of cations included a low-capacity, sulfonated polystyrene/ divinylbenzene ...