Recently, heme protein cavity mutants have been engineered in which the proximal coordinating amino acid has been replaced by a smaller, noncoordinating residue leaving a cavity that can be filled by exogenous axial ligands. This approach was pioneered by Barrick (Biochemistry 1994, 33, 6546-6554) with H93G sperm whale myoglobin where the coordinating histidine is replaced by glycine and the pr...

Uniform metal iron ellipsoidal particles of around 200 nm in length were obtained by reduction and passivation of alumina-coated a – Fe2O3 ~hematite! particles under different conditions of temperature and hydrogen flow rate. The monodispersed hematite particles were prepared by the controlled hydrolysis of ferric sulfate and further coated with a homogeneous thin layer of Al2O3 by careful sele...

I describe a simple, rapid technique for saturating the transferrin in serum and then removing unbound (excess) iron. This technique involves use of an easily prepared column of basic chromatographic alumina and a saturating solution of ferric chloride in citric acid. This method, when compared with the magnesium carbonate method of Ramsay (Clin. Chim. Acta 2: 221, 1957) by regression analysis ...

Wastewater management in two companies representing the pharmaceutical industry was investigated and implemented. The results showed that the integration of the pollution prevention approach followed by an equalization tank reduced the organic load up to 70%, while further chemical treatment using either alum or ferric chloride aided with lime produced a quality of effluent suitable for restric...

The goal of this study was to determine the removal efficiencies of chromium, copper, lead, nickel, and zinc from raw wastewater by chemically enhanced primary treatment (CEPT) and to attain a total suspended solids removal goal of 80%. Operating parameters and chemical doses were optimized by bench-scale tests. Locally obtained raw wastewater samples were spiked with heavy metal solutions to o...

Alumina-rich iron ore is a widely existed polymetallic deposit in the nature, and it has a high comprehensive utilization value. Because the alumina and iron contents of alumina-rich iron ore vary from each other, there are many different measures and processes to recover iron and alumina from the various kinds of alumina-rich iron ore. In the blast furnace (BF) ironmaking process, the alumina ...

Abstract Colloidal ferric oxide/aluminum nanothermite mixture was incorporated into ammonium percholorate (AP). Nanothermite particles experienced an increase in AP decomposition enthalpy by 120% using DSC. Decomposition kinetic study performed integral isoconversional models including Kissinger and KAS models. offered decrease activation energy 55 44% models, respectively. nanocomposite is run...