We report on the grafting of coumarin chromophores on flat silicon surfaces and in regions of nanometric dimensions drawn on silicon surfaces. The coumarin derivative was grafted by using the quaternization of a tertiary amine group of the chromophore with a ((chloromethyl)phenylethyl)-dimethylchlorosilane (CMPDCS) grafted on silicon. Complete characterization of the grafted layer was performed...

A magnetic adsorbent can be easily recovered from treated water by magnetic force, without requiring further downstream treatment. In this research, amine-functionalized silica magnetite has been synthesized using N-[3-(trimethoxysilyl)propyl]-ethylenediamine (TPED) as a surface modification agent. The synthesized magnetic amine adsorbents were used to adsorb copper ions in an aqueous solution ...

Biochar-based carbonaceous adsorbents are gaining interest due to their high availability, ease of modification, and low cost; however, they show limited adsorption CO2 in flue gas common textural properties. In this study, TEPA-modified biochar was used prepare a solid amine adsorbent for the efficient capture gas. First, porous prepared with FeCl3, Mg(NO3)2, H2O (g) as activators walnut shell...

As the designs of polymer systems used to deliver nucleic acids continue to evolve, it is becoming increasingly apparent that the basic bulk manufacturing techniques of the past will be insufficient to produce polymer-nucleic acid nanocomplexes that possess the uniformity, stability, and potency required for their successful clinical translation and widespread commercialization. Traditional bul...

background chitin and its derivatives (chitosan) are natural biopolymer produced from crustacean shell, which due to their active functional groups such as amine and hydroxyl have high ability to absorb heavy metals from water and wastewater. the aim of this study was to investigate zinc removal from aqueous solutions by using chitin extracted from shrimp shells. material and methods to study t...

Abstract A cellulosic material has been synthesized that could efficiently and selectively adsorb organic inorganic contaminants from aqueous solutions without interference competing adsorption sites. Cellulose-graft-tetraethylenepentamine molecular imprinted polymer (C-TEPA-MIP) was by using 4-nitrophenol (4-NP) as the template. The C-TEPA-MIP adsorbent 4-NP Cr(VI) simultaneously selectively, ...

in this study, a novel solid dendrimer amine (hyperbranched polymers) was prepared using mesoporous carbon nitride functionalized by melamine based dendrimer amines. this adsorbent was denoted mda-mcn-1. the process was stepwise synthesis and hard-templating method using mesoporous silica sba-15 as a template. cyanuric chloride and n,n-diisopropylethylamine (dipea, merck) were used for function...