Ultrasonic velocity and density values have been measured at 303 K in binary mixtures containing aniline, toluene and n-butanol; and the thermodynamical approach is applied to evaluate the mixtures’ molar volume, adiabatic compressibility, intermolecular free length and excess values. The observed results are interpreted in terms of molecular interaction between the components of the mixtures. ...

A new, simple and rapid method based on the principle of liquid-liquid phase equilibria has been developed for the analysis of binary mixtures of chemically similar organic compounds. The method does not require elaborate instrumentation and can be used to analyse mixtures of members of homologous series. The application of the method has been illustrated by analysing binary mixtures of n-hexan...